Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.5194/acp-19-8547-2019 |
An improved estimate for the delta C-13 and delta O-18 signatures of carbon monoxide produced from atmospheric oxidation of volatile organic compounds | |
Vimont, Isaac J.1,2,3; Turnbull, Jocelyn C.3,4; Petrenko, Vasilii V.5; Place, Philip F.5; Sweeney, Colm2; Miles, Natasha6; Richardson, Scott6; Vaughn, Bruce H.1; White, James W. C.1 | |
2019-07-05 | |
发表期刊 | ATMOSPHERIC CHEMISTRY AND PHYSICS
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ISSN | 1680-7316 |
EISSN | 1680-7324 |
出版年 | 2019 |
卷号 | 19期号:13页码:8547-8562 |
文章类型 | Article |
语种 | 英语 |
国家 | USA; New Zealand |
英文摘要 | Atmospheric carbon monoxide (CO) is a key player in global atmospheric chemistry and a regulated pollutant in urban areas. Oxidation of volatile organic compounds (VOCs) is an important component of the global CO budget and has also been hypothesized to contribute substantially to the summertime urban CO budget. In principle, stable isotopic analysis of CO could constrain the magnitude of this source. However, the isotopic signature of VOC-produced CO has not been well quantified, especially for the oxygen isotopes. We performed measurements of CO stable isotopes on air samples from two sites around Indianapolis, US, over three summers to investigate the isotopic signature of VOC-produced CO. One of the sites is located upwind of the city, allowing us to quantitatively remove the background air signal and isolate the urban CO enhancements. as well as the isotopic signature of these enhancements. In addition, we use measurements of Delta(CO2)-C-14 in combination with the CO : CO2 emission ratio from fossil fuels to constrain the fossil-fuel-derived CO and thereby isolate the VOC-derived component of the CO enhancement. Combining these measurements and analyses, we are able to determine the carbon and oxygen isotopic signatures of CO derived from VOC oxidation as -32.8 parts per thousand +/- 0.5 parts per thousand and 3.6 parts per thousand +/- 1.2 parts per thousand, respectively. Additionally, we analyzed CO stable isotopes for 1 year at Beech Island, South Carolina, US, a site thought to have large VOC-derived contributions to the summertime CO budget. The Beech Island results are consistent with isotopic signatures of VOC-derived CO determined from the Indianapolis data. This study represents the first direct determination of the isotopic signatures of VOC-derived CO and will allow for improved use of isotopes in constraining the global and regional CO budgets. |
领域 | 地球科学 |
收录类别 | SCI-E |
WOS记录号 | WOS:000474258600001 |
WOS关键词 | FOSSIL-FUEL CO2 ; ISOTOPIC COMPOSITION ; NONMETHANE HYDROCARBONS ; FRACTIONATION ; ISOPRENE ; OXYGEN ; MODEL ; O-18 ; C-13 ; CHEMISTRY |
WOS类目 | Environmental Sciences ; Meteorology & Atmospheric Sciences |
WOS研究方向 | Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/184911 |
专题 | 地球科学 |
作者单位 | 1.Univ Colorado, Inst Arctic & Alpine Res, Boulder, CO 80309 USA; 2.NOAA, Global Monitoring Div, Boulder, CO 80305 USA; 3.Univ Colorado, CIRES, Boulder, CO 80309 USA; 4.GNS Sci, Lower Hutt, New Zealand; 5.Univ Rochester, Earth & Environm Sci Dept, Rochester, NY USA; 6.Penn State Univ, Dept Meteorol & Atmospher Sci, College Stn, TX USA |
推荐引用方式 GB/T 7714 | Vimont, Isaac J.,Turnbull, Jocelyn C.,Petrenko, Vasilii V.,et al. An improved estimate for the delta C-13 and delta O-18 signatures of carbon monoxide produced from atmospheric oxidation of volatile organic compounds[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2019,19(13):8547-8562. |
APA | Vimont, Isaac J..,Turnbull, Jocelyn C..,Petrenko, Vasilii V..,Place, Philip F..,Sweeney, Colm.,...&White, James W. C..(2019).An improved estimate for the delta C-13 and delta O-18 signatures of carbon monoxide produced from atmospheric oxidation of volatile organic compounds.ATMOSPHERIC CHEMISTRY AND PHYSICS,19(13),8547-8562. |
MLA | Vimont, Isaac J.,et al."An improved estimate for the delta C-13 and delta O-18 signatures of carbon monoxide produced from atmospheric oxidation of volatile organic compounds".ATMOSPHERIC CHEMISTRY AND PHYSICS 19.13(2019):8547-8562. |
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