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DOI | 10.1029/2019GL083472 |
First-Principles Determination of the Dissociation Phase Boundary of Phase H MgSiO4H2 | |
Tsuchiya, Jun1,2; Umemoto, Koichiro2 | |
2019-07-16 | |
发表期刊 | GEOPHYSICAL RESEARCH LETTERS |
ISSN | 0094-8276 |
EISSN | 1944-8007 |
出版年 | 2019 |
卷号 | 46期号:13页码:7333-7336 |
文章类型 | Article |
语种 | 英语 |
国家 | Japan |
英文摘要 | Phase H (MgSiO4H2) is considered an important carrier of water into the lower mantle by the subduction of slabs. This phase has been reported to decompose into H2O ice VII and MgSiO3 bridgmanite under pressure. However, the dissociation phase boundary under the mantle pressure and temperature conditions has not been determined thus far. In this work, the dissociation phase boundary of phase H is determined by the calculation of Gibbs free energy of H2O ice VII. The stability field of phase H is found to be significantly extended from 52 to 62 GPa by the inclusion of zero-point vibrational energy. Phase H decomposes into MgSiO3 bridgmanite and H2O ice VII at approximately 60 GPa (at similar to 1000 K). This result indicates that the transportation of water by dense hydrous magnesium silicates may be terminated at a depth of approximately 1,500 km in the middle of the lower mantle in a pure Mg-endmember composition. |
领域 | 气候变化 |
收录类别 | SCI-E |
WOS记录号 | WOS:000476960100031 |
WOS关键词 | WATER TRANSPORT ; ICE ; STABILITY ; SILICATE ; H2O |
WOS类目 | Geosciences, Multidisciplinary |
WOS研究方向 | Geology |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/185050 |
专题 | 气候变化 |
作者单位 | 1.Ehime Univ, Geodynam Res Ctr, Matsuyama, Ehime, Japan; 2.Tokyo Inst Technol, Earth Life Sci Inst, Tokyo, Japan |
推荐引用方式 GB/T 7714 | Tsuchiya, Jun,Umemoto, Koichiro. First-Principles Determination of the Dissociation Phase Boundary of Phase H MgSiO4H2[J]. GEOPHYSICAL RESEARCH LETTERS,2019,46(13):7333-7336. |
APA | Tsuchiya, Jun,&Umemoto, Koichiro.(2019).First-Principles Determination of the Dissociation Phase Boundary of Phase H MgSiO4H2.GEOPHYSICAL RESEARCH LETTERS,46(13),7333-7336. |
MLA | Tsuchiya, Jun,et al."First-Principles Determination of the Dissociation Phase Boundary of Phase H MgSiO4H2".GEOPHYSICAL RESEARCH LETTERS 46.13(2019):7333-7336. |
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