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DOI10.1126/science.aai8034
Active sites in heterogeneous ice nucleation-the example of K-rich feldspars
Kiselev, Alexei1; Bachmann, Felix1,2; Pedevilla, Philipp3,4; Cox, Stephen J.3,4; Michaelides, Angelos3; Gerthsen, Dagmar2; Leisner, Thomas1,5
2017-01-27
发表期刊SCIENCE
ISSN0036-8075
EISSN1095-9203
出版年2017
卷号355期号:6323页码:367-371
文章类型Article
语种英语
国家Germany; Canada
英文摘要

Ice formation on aerosol particles is a process of crucial importance to Earth's climate and the environmental sciences, but it is not understood at the molecular level. This is partly because the nature of active sites, local surface features where ice growth commences, is still unclear. Here we report direct electron-microscopic observations of deposition growth of aligned ice crystals on feldspar, an atmospherically important component of mineral dust. Our molecular-scale computer simulations indicate that this alignment arises from the preferential nucleation of prismatic crystal planes of ice on high-energy (100) surface planes of feldspar. The microscopic patches of (100) surface, exposed at surface defects such as steps, cracks, and cavities, are thought to be responsible for the high ice nucleation efficacy of potassium (K)-feldspar particles.


领域地球科学 ; 气候变化 ; 资源环境
收录类别SCI-E
WOS记录号WOS:000393172800031
WOS关键词CRYSTAL NUCLEATION ; EPITAXIAL-GROWTH ; WATER-ADSORPTION ; KAOLINITE ; SURFACES ; DEPOSITION ; PARTICLES ; MINERALS ; DUST ; MORPHOLOGY
WOS类目Multidisciplinary Sciences
WOS研究方向Science & Technology - Other Topics
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文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/195308
专题地球科学
资源环境科学
气候变化
作者单位1.Karlsruhe Inst Technol KIT, Inst Meteorol & Climate Res IMK AAF, Atmospher Aerosol Res Dept, Hermann Helmholtz Platz, Karlsruhe, Germany;
2.KIT, Lab Elect Microscopy LEM, Engesserstrasse 7, D-76131 Karlsruhe, Germany;
3.Univ Coll London UCL, Thomas Young Ctr, London Ctr Nanotechnol, 17-19 Gordon St, London, ON WC1H 0AH, Canada;
4.Univ Coll London UCL, Dept Phys & Astron, 17-19 Gordon St, London, ON WC1H 0AH, Canada;
5.Heidelberg Univ, Inst Umweltphys, Im Neuenheimer Feld 229, Heidelberg, Germany
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Kiselev, Alexei,Bachmann, Felix,Pedevilla, Philipp,et al. Active sites in heterogeneous ice nucleation-the example of K-rich feldspars[J]. SCIENCE,2017,355(6323):367-371.
APA Kiselev, Alexei.,Bachmann, Felix.,Pedevilla, Philipp.,Cox, Stephen J..,Michaelides, Angelos.,...&Leisner, Thomas.(2017).Active sites in heterogeneous ice nucleation-the example of K-rich feldspars.SCIENCE,355(6323),367-371.
MLA Kiselev, Alexei,et al."Active sites in heterogeneous ice nucleation-the example of K-rich feldspars".SCIENCE 355.6323(2017):367-371.
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