Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.1126/science.aaf7230 |
Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry | |
Choi, Junwon1; Fu, Gregory C.2 | |
2017-04-14 | |
发表期刊 | SCIENCE
![]() |
ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2017 |
卷号 | 356期号:6334 |
文章类型 | Review |
语种 | 英语 |
国家 | USA |
英文摘要 | Because the backbone of most organic molecules is composed primarily of carbon-carbon bonds, the development of efficient methods for their construction is one of the central challenges of organic synthesis. Transition metal-catalyzed cross-coupling reactions between organic electrophiles and nucleophiles serve as particularly powerful tools for achieving carbon-carbon bond formation. Until recently, the vast majority of cross-coupling processes had used either aryl or alkenyl electrophiles as one of the coupling partners. In the past 15 years, versatile new methods have been developed that effect cross-couplings of an array of alkyl electrophiles, thereby greatly expanding the diversity of target molecules that are readily accessible. The ability to couple alkyl electrophiles opens the door to a stereochemical dimension-specifically, enantioconvergent couplings of racemic electrophiles-that substantially enhances the already remarkable utility of cross-coupling processes. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000399013800025 |
WOS关键词 | NEGISHI REACTIONS ; ORGANOMANGANESE(II) COMPLEXES ; HOMOGENEOUS CATALYSTS ; SUZUKI REACTIONS ; HALIDES ; BROMIDES ; BETA ; ELECTROPHILES ; ALLYLATION ; IODIDES |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/195822 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | 1.Stanford Univ, Dept Chem, Stanford, CA 94305 USA; 2.CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA |
推荐引用方式 GB/T 7714 | Choi, Junwon,Fu, Gregory C.. Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry[J]. SCIENCE,2017,356(6334). |
APA | Choi, Junwon,&Fu, Gregory C..(2017).Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry.SCIENCE,356(6334). |
MLA | Choi, Junwon,et al."Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry".SCIENCE 356.6334(2017). |
条目包含的文件 | 条目无相关文件。 |
个性服务 |
推荐该条目 |
保存到收藏夹 |
查看访问统计 |
导出为Endnote文件 |
谷歌学术 |
谷歌学术中相似的文章 |
[Choi, Junwon]的文章 |
[Fu, Gregory C.]的文章 |
百度学术 |
百度学术中相似的文章 |
[Choi, Junwon]的文章 |
[Fu, Gregory C.]的文章 |
必应学术 |
必应学术中相似的文章 |
[Choi, Junwon]的文章 |
[Fu, Gregory C.]的文章 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论