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DOI | 10.1126/science.aam8310 |
Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration | |
Cadiau, Amandine1; Belmabkhout, Youssef1; Adil, Karim1; Bhatt, Prashant M.1; Pillai, Renjith S.1; Shkurenko, Aleksander1; Martineau-Corcos, Charlotte2,3; Maurin, Guillaume4; Eddaoudi, Mohamed1 | |
2017-05-19 | |
发表期刊 | SCIENCE
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ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2017 |
卷号 | 356期号:6339页码:731-735 |
文章类型 | Article |
语种 | 英语 |
国家 | Saudi Arabia; France |
英文摘要 | Natural gas must be dehydrated before it can be transported and used, but conventional drying agents such as activated alumina or inorganic molecular sieves require an energy-intensive desiccant-regeneration step. We report a hydrolytically stable fluorinated metal-organic framework, AlFFIVE-1-Ni (KAUST-8), with a periodic array of open metal coordination sites and fluorine moieties within the contracted square-shaped one-dimensional channel. This material selectively removed water vapor from gas streams containing CO2, N-2, CH4, and higher hydrocarbons typical of natural gas, as well as selectively removed both H2O and CO2 in N-2-containing streams. The complete desorption of the adsorbed water molecules contained by the AlFFIVE-1-Ni sorbent requires relatively moderate temperature (similar to 105 degrees C) and about half the energy input for commonly used desiccants. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000401508400042 |
WOS关键词 | INITIO STRUCTURE DETERMINATION ; ADSORPTION ; DEHUMIDIFICATION ; REMOVAL ; DESIGN |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/196081 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | 1.King Abdullah Univ Sci & Technol, Div Phys Sci & Engn PSE, Adv Membrane & Porous Mat AMPM, Funct Mat Design Discovery & Dev FMD3, Thuwal 239556900, Saudi Arabia; 2.Univ Versailles St Quentin Yvelines UVSQ, Inst Lavoisier Versailles ILV, UMR CNRS 8180, 45 Ave Etats Unis, F-78035 Versailles, France; 3.CNRS, CEMHTI, UPR 3079, 1D Ave Rech Sci, F-45071 Orleans 2, France; 4.Univ Montpellier, Inst Charles Gerhardt Montpellier UMR CNRS 5253, Pl Eugene Bataillon, F-34095 Montpellier 05, France |
推荐引用方式 GB/T 7714 | Cadiau, Amandine,Belmabkhout, Youssef,Adil, Karim,et al. Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration[J]. SCIENCE,2017,356(6339):731-735. |
APA | Cadiau, Amandine.,Belmabkhout, Youssef.,Adil, Karim.,Bhatt, Prashant M..,Pillai, Renjith S..,...&Eddaoudi, Mohamed.(2017).Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration.SCIENCE,356(6339),731-735. |
MLA | Cadiau, Amandine,et al."Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration".SCIENCE 356.6339(2017):731-735. |
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