GSTDTAP  > 地球科学
DOI10.1126/science.aal4263
Liquefied gas electrolytes for electrochemical energy storage devices
Rustomji, Cyrus S.1; Yang, Yangyuchen2; Kim, Tae Kyoung2; Mac, Jimmy1; Kim, Young Jin2; Caldwell, Elizabeth2; Chung, Hyeseung1; Meng, Shirley1
2017-06-30
发表期刊SCIENCE
ISSN0036-8075
EISSN1095-9203
出版年2017
卷号356期号:6345
文章类型Article
语种英语
国家USA
英文摘要

Electrochemical capacitors and lithium-ion batteries have seen little change in their electrolyte chemistry since their commercialization, which has limited improvements in device performance. Combining superior physical and chemical properties and a high dielectric-fluidity factor, the use of electrolytes based on solvent systems that exclusively use components that are typically gaseous under standard conditions show a wide potential window of stability and excellent performance over an extended temperature range. Electrochemical capacitors using difluoromethane show outstanding performance from -78 degrees to + 65 degrees C, with an increased operation voltage. The use of fluoromethane shows a high coulombic efficiency of similar to 97% for cycling lithium metal anodes, together with good cyclability of a 4-volt lithium cobalt oxide cathode and operation as low as -60 degrees C, with excellent capacity retention.


领域地球科学 ; 气候变化 ; 资源环境
收录类别SCI-E
WOS记录号WOS:000404351500029
WOS关键词LOW-TEMPERATURE PERFORMANCE ; DOUBLE-LAYER CAPACITORS ; 1,1,1,2-TETRAFLUOROETHANE HFC 134A ; LI-ION CELLS ; DIELECTRIC-CONSTANT ; LITHIUM METAL ; SUPERCRITICAL TRIFLUOROMETHANE ; ELECTRICAL-CONDUCTIVITY ; AMMONIA SOLUTIONS ; ORGANIC ESTERS
WOS类目Multidisciplinary Sciences
WOS研究方向Science & Technology - Other Topics
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文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/196365
专题地球科学
资源环境科学
气候变化
作者单位1.Univ Calif San Diego, Dept Nano Engn, La Jolla, CA 92121 USA;
2.Univ Calif San Diego, Mat Sci & Engn Program, Dept Mech & Aerosp Engn, La Jolla, CA 92121 USA
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GB/T 7714
Rustomji, Cyrus S.,Yang, Yangyuchen,Kim, Tae Kyoung,et al. Liquefied gas electrolytes for electrochemical energy storage devices[J]. SCIENCE,2017,356(6345).
APA Rustomji, Cyrus S..,Yang, Yangyuchen.,Kim, Tae Kyoung.,Mac, Jimmy.,Kim, Young Jin.,...&Meng, Shirley.(2017).Liquefied gas electrolytes for electrochemical energy storage devices.SCIENCE,356(6345).
MLA Rustomji, Cyrus S.,et al."Liquefied gas electrolytes for electrochemical energy storage devices".SCIENCE 356.6345(2017).
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