GSTDTAP  > 地球科学
DOI10.1126/science.aau5105
Frontiers in molecular p-block chemistry: From structure to reactivity
Melen, Rebecca L.
2019-02-01
发表期刊SCIENCE
ISSN0036-8075
EISSN1095-9203
出版年2019
卷号363期号:6426页码:479-+
文章类型Review
语种英语
国家Wales
英文摘要

This year marks the 350th anniversary of the discovery of phosphorus by the alchemist Hennig Brand. However, this element was not included in the p-block of the periodic table until more recently. 2019 also marks the 150th anniversary of the preliminary tabular arrangement of the elements into the periodic system by Mendeleev. Of the 63 elements known in 1869, almost one-third of them belonged to what ultimately became the p-block, and Mendeleev predicted the existence of both gallium and germanium as well. The elements of the p-block have a disparate and varied history. Their chemical structure, reactivity, and properties vary widely. Nevertheless, in recent years, a better understanding of trends in p-block reactivity, particularly the behavior of those elements not typically found in biological systems, has led to a promising array of emerging applications, highlighted herein.


领域地球科学 ; 气候变化 ; 资源环境
收录类别SCI-E
WOS记录号WOS:000457409400038
WOS关键词MAIN-GROUP ELEMENTS ; ACTIVATION ; HYDROGENATION ; CATALYSIS ; BORON ; PHOSPHORUS ; REDUCTION ; COMPOUND ; NITROGEN ; ACID
WOS类目Multidisciplinary Sciences
WOS研究方向Science & Technology - Other Topics
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文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/200667
专题地球科学
资源环境科学
气候变化
作者单位Cardiff Univ, Sch Chem, Main Bldg,Pk Pl, Cardiff CF10 3AT, S Glam, Wales
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Melen, Rebecca L.. Frontiers in molecular p-block chemistry: From structure to reactivity[J]. SCIENCE,2019,363(6426):479-+.
APA Melen, Rebecca L..(2019).Frontiers in molecular p-block chemistry: From structure to reactivity.SCIENCE,363(6426),479-+.
MLA Melen, Rebecca L.."Frontiers in molecular p-block chemistry: From structure to reactivity".SCIENCE 363.6426(2019):479-+.
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