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DOI | 10.1126/science.aau5105 |
Frontiers in molecular p-block chemistry: From structure to reactivity | |
Melen, Rebecca L. | |
2019-02-01 | |
发表期刊 | SCIENCE
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ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2019 |
卷号 | 363期号:6426页码:479-+ |
文章类型 | Review |
语种 | 英语 |
国家 | Wales |
英文摘要 | This year marks the 350th anniversary of the discovery of phosphorus by the alchemist Hennig Brand. However, this element was not included in the p-block of the periodic table until more recently. 2019 also marks the 150th anniversary of the preliminary tabular arrangement of the elements into the periodic system by Mendeleev. Of the 63 elements known in 1869, almost one-third of them belonged to what ultimately became the p-block, and Mendeleev predicted the existence of both gallium and germanium as well. The elements of the p-block have a disparate and varied history. Their chemical structure, reactivity, and properties vary widely. Nevertheless, in recent years, a better understanding of trends in p-block reactivity, particularly the behavior of those elements not typically found in biological systems, has led to a promising array of emerging applications, highlighted herein. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000457409400038 |
WOS关键词 | MAIN-GROUP ELEMENTS ; ACTIVATION ; HYDROGENATION ; CATALYSIS ; BORON ; PHOSPHORUS ; REDUCTION ; COMPOUND ; NITROGEN ; ACID |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/200667 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | Cardiff Univ, Sch Chem, Main Bldg,Pk Pl, Cardiff CF10 3AT, S Glam, Wales |
推荐引用方式 GB/T 7714 | Melen, Rebecca L.. Frontiers in molecular p-block chemistry: From structure to reactivity[J]. SCIENCE,2019,363(6426):479-+. |
APA | Melen, Rebecca L..(2019).Frontiers in molecular p-block chemistry: From structure to reactivity.SCIENCE,363(6426),479-+. |
MLA | Melen, Rebecca L.."Frontiers in molecular p-block chemistry: From structure to reactivity".SCIENCE 363.6426(2019):479-+. |
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