GSTDTAP  > 地球科学
DOI10.1126/science.aav3506
What would it take for renewably powered electrosynthesis to displace petrochemical processes?
De Luna, Phil1,2,3; Hahn, Christopher2,4; Higgins, Drew2,4,5; Jaffer, Shaffiq A.6; Jaramillo, Thomas F.2,4; Sargent, Edward H.7
2019-04-26
发表期刊SCIENCE
ISSN0036-8075
EISSN1095-9203
出版年2019
卷号364期号:6438页码:350-+
文章类型Review
语种英语
国家Canada; USA
英文摘要

Electrocatalytic transformation of carbon dioxide (CO2) and water into chemical feedstocks offers the potential to reduce carbon emissions by shifting the chemical industry away from fossil fuel dependence. We provide a technoeconomic and carbon emission analysis of possible products, offering targets that would need to be met for economically compelling industrial implementation to be achieved. We also provide a comparison of the projected costs and CO2 emissions across electrocatalytic, biocatalytic, and fossil fuel-derived production of chemical feedstocks. We find that for electrosynthesis to become competitive with fossil fuel-derived feedstocks, electrical-to-chemical conversion efficiencies need to reach at least 60%, and renewable electricity prices need to fall below 4 cents per kilowatt-hour. We discuss the possibility of combining electro- and biocatalytic processes, using sequential upgrading of CO2 as a representative case. We describe the technical challenges and economic barriers to marketable electrosynthesized chemicals.


领域地球科学 ; 气候变化 ; 资源环境
收录类别SCI-E
WOS记录号WOS:000465643400035
WOS关键词ELECTROCHEMICAL CO2 REDUCTION ; LOW-OVERPOTENTIAL ELECTROREDUCTION ; LIFE-CYCLE ASSESSMENT ; CARBON-DIOXIDE ; HYDROGEN-PRODUCTION ; TECHNOECONOMIC ANALYSIS ; SYNGAS FERMENTATION ; SELECTIVE FORMATION ; ETHYLENE PRODUCTION ; FORMIC-ACID
WOS类目Multidisciplinary Sciences
WOS研究方向Science & Technology - Other Topics
引用统计
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/201297
专题地球科学
资源环境科学
气候变化
作者单位1.Univ Toronto, Dept Mat Sci & Engn, Toronto, ON M5S 3E4, Canada;
2.Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA;
3.Natl Res Council Canada, Ottawa, ON K1N 0R6, Canada;
4.SLAC Natl Accelerator Lab, SUNCAT Ctr Interface Sci & Catalysis, Menlo Pk, CA 94025 USA;
5.McMaster Univ, Dept Chem Engn, Hamilton, ON L8S 4L8, Canada;
6.TOTAL Amer Serv Inc, Hopkinton, MA 01748 USA;
7.Univ Toronto, Dept Elect & Comp Engn, Toronto, ON M5S 3G4, Canada
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GB/T 7714
De Luna, Phil,Hahn, Christopher,Higgins, Drew,et al. What would it take for renewably powered electrosynthesis to displace petrochemical processes?[J]. SCIENCE,2019,364(6438):350-+.
APA De Luna, Phil,Hahn, Christopher,Higgins, Drew,Jaffer, Shaffiq A.,Jaramillo, Thomas F.,&Sargent, Edward H..(2019).What would it take for renewably powered electrosynthesis to displace petrochemical processes?.SCIENCE,364(6438),350-+.
MLA De Luna, Phil,et al."What would it take for renewably powered electrosynthesis to displace petrochemical processes?".SCIENCE 364.6438(2019):350-+.
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