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DOI | 10.1038/nature24012 |
Exploiting non-covalent pi interactions for catalyst design | |
Neel, Andrew J.1,2,4; Hilton, Margaret J.3; Sigman, Matthew S.3; Toste, F. Dean1,2 | |
2017-03-30 | |
发表期刊 | NATURE |
ISSN | 0028-0836 |
EISSN | 1476-4687 |
出版年 | 2017 |
卷号 | 543期号:7647页码:637-646 |
文章类型 | Review |
语种 | 英语 |
国家 | USA |
英文摘要 | Molecular recognition, binding and catalysis are often mediated by non-covalent interactions involving aromatic functional groups. Although the relative complexity of these so-called pi interactions has made them challenging to study, theory and modelling have now reached the stage at which we can explain their physical origins and obtain reliable insight into their effects on molecular binding and chemical transformations. This offers opportunities for the rational manipulation of these complex non-covalent interactions and their direct incorporation into the design of small-molecule catalysts and enzymes. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000397619700042 |
WOS关键词 | AROMATIC STACKING INTERACTIONS ; LONE-PAIR ; ASYMMETRIC CATALYSIS ; AB-INITIO ; SUPRAMOLECULAR COMPLEXES ; TRANSFER HYDROGENATION ; ENOLATE CHEMISTRY ; SQUALENE CYCLASE ; ANION-CATALYSIS ; ACIDIC SURFACES |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/202818 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | 1.Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA; 2.Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA; 3.Univ Utah, Dept Chem, 315 South 1400 East, Salt Lake City, UT 84112 USA; 4.Merck & Co Inc, Dept Proc Chem, Rahway, NJ 07065 USA |
推荐引用方式 GB/T 7714 | Neel, Andrew J.,Hilton, Margaret J.,Sigman, Matthew S.,et al. Exploiting non-covalent pi interactions for catalyst design[J]. NATURE,2017,543(7647):637-646. |
APA | Neel, Andrew J.,Hilton, Margaret J.,Sigman, Matthew S.,&Toste, F. Dean.(2017).Exploiting non-covalent pi interactions for catalyst design.NATURE,543(7647),637-646. |
MLA | Neel, Andrew J.,et al."Exploiting non-covalent pi interactions for catalyst design".NATURE 543.7647(2017):637-646. |
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