Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.1038/s41467-018-04755-y |
Cross-coupling polycondensation via C-O or C-N bond cleavage | |
Yang, Ze-Kun1,2; Xu, Ning-Xin1; Takita, Ryo2; Muranaka, Atsuya2; Wang, Chao1,2; Uchiyama, Masanobu1,2 | |
2018-04-23 | |
发表期刊 | NATURE COMMUNICATIONS
![]() |
ISSN | 2041-1723 |
出版年 | 2018 |
卷号 | 9 |
文章类型 | Article |
语种 | 英语 |
国家 | Japan |
英文摘要 | pi-Conjugated polymers are widely used in optoelectronics for fabrication of organic photovoltaic devices, organic light-emitting diodes, organic field effect transistors, and so on. Here we describe the protocol for polycondensation of bifunctional aryl ethers or aryl ammonium salts with aromatic dimetallic compounds through cleavage of inert C-O/C-N bonds. This reaction proceeds smoothly in the presence of commercially available Ni/Pd catalyst under mild conditions, affording the corresponding pi-conjugated polymers with high molecular weight. The method is applicable to monomers that are unreactive in other currently employed polymerization procedures, and opens up the possibility of transforming a range of naturally abundant chemicals into useful functional compounds/polymers. |
领域 | 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000430541900003 |
WOS关键词 | CARBON-CARBON BONDS ; NICKEL-INDUCED CONVERSION ; ONE-STEP TRANSFORMATIONS ; ARYL ALKYL ETHERS ; CATALYZED BORYLATION ; REDUCTIVE CLEAVAGE ; GRIGNARD-REAGENTS ; AMMONIUM-SALTS ; METHYL ETHERS ; OXYGEN BOND |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/203846 |
专题 | 资源环境科学 |
作者单位 | 1.Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan; 2.RIKEN, Adv Elements Chem Lab, CPR, 2-1 Hirosawa, Wako, Saitama 3510198, Japan |
推荐引用方式 GB/T 7714 | Yang, Ze-Kun,Xu, Ning-Xin,Takita, Ryo,et al. Cross-coupling polycondensation via C-O or C-N bond cleavage[J]. NATURE COMMUNICATIONS,2018,9. |
APA | Yang, Ze-Kun,Xu, Ning-Xin,Takita, Ryo,Muranaka, Atsuya,Wang, Chao,&Uchiyama, Masanobu.(2018).Cross-coupling polycondensation via C-O or C-N bond cleavage.NATURE COMMUNICATIONS,9. |
MLA | Yang, Ze-Kun,et al."Cross-coupling polycondensation via C-O or C-N bond cleavage".NATURE COMMUNICATIONS 9(2018). |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论