Mechanochemical Processes dictating Calcite&#39;s Frictional Characteristics

GSTDTAP

项目编号	1856525
	Mechanochemical Processes dictating Calcite's Frictional Characteristics
	Rosa Espinosa-Marzal (Principal Investigator)
主持机构	University of Illinois at Urbana-Champaign
项目开始年	2019
	2019-07-15
项目结束日期	2022-06-30
资助机构	US-NSF
项目类别	Standard Grant
项目经费	323914(USD)
国家	美国
语种	英语
英文摘要	Earthquakes are recurring and devastating events. To predict accurately their occurrence and magnitude remains, however, difficult. This is because the mechanisms underlying the rupture of earthquake-generating faults are not fully understood. Water plays an important role in fault dynamics; yet, the complexity of fault interfaces has hindered identifying the specific mechanisms influencing fault behaviors. Here, the researchers investigate the frictional strength of calcite - a mineral found in fault gouges - in aqueous environment. To study the effects of water-rich fluids, they use an idealized grain interface consisting of two 1-mm single crystals sliding against each other, with or without fluids in between them. The interface contains asperity contacts characterized at the microscale by atomic force microscopy. The study is relevant to natural faults because the stresses and slip rates applied to the interface are comparable to those of geological settings. Frictional characteristics are quantified using a new technique which measures displacements with an accuracy of 1 angstrom (0.1 millionth of a mm). This allows investigating the involved mechanisms, such as crystal dissolution/recrystallization on contacts. The project's results improve models of fault friction, which contributes improving the assessment of seismic hazards in the presence of reactive fluids. This project promotes support for a graduate student, training for undergraduate students and outreach to K-12 students, notably from groups underrepresented in Science. The team follows two main lines of research. At the experimental level, the project advances the knowledge of mechano-chemical interfacial reactions and their influence on calcite's frictional characteristics. It informs the mechanisms underlying pressure-solution at grain boundaries. The influence of different factors is evaluated: fluid chemistry, surface electric potential, the presence of phyllosilicates or confined fluid films. The effects of sliding velocity, stress, temperature, contact time and topography, on friction and adhesion are also quantified. Essential to this work is a modification of the Surface Forces Apparatus. The new development allows measuring creep deformation at wet calcite contacts with a precision of 0.1 nm, as well as interfacial forces (disjoining pressure, adhesion and friction). This provides insight on the relationship between pressure-solution creep and static and dynamic friction over a wide range of conditions. The simple geometry of the experiments allows to investigate the microscopic mechanisms responsible for macroscopic friction, and to test the theories that describe them. At the theoretical level, friction at single- and multi-asperity contacts are modeled based on the shear-assisted thermally activated slip theory, accounting for contact aging due to pressure-solution creep. The new model parameters are compared to and tested against the rate-and-state friction constitutive equations and their empirical parameters. The project, thus, fills the gap between the microscopic and the macroscopic scales in the understanding of fault friction in aqueous environment. This award is co-funded by the Prediction of and Resilience against Extreme Events (PREEVENTS) program. This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
文献类型	项目
条目标识符	http://119.78.100.173/C666/handle/2XK7JSWQ/213448
专题	环境与发展全球科技态势
推荐引用方式 GB/T 7714	Rosa Espinosa-Marzal .Mechanochemical Processes dictating Calcite's Frictional Characteristics.2019.