GSTDTAP  > 地球科学
DOI10.5194/acp-20-3209-2020
Technical note: Fundamental aspects of ice nucleation via pore condensation and freezing including Laplace pressure and growth into macroscopic ice
Marcolli, Claudia
2020-03-17
发表期刊ATMOSPHERIC CHEMISTRY AND PHYSICS
ISSN1680-7316
EISSN1680-7324
出版年2020
卷号20期号:5页码:3209-3230
文章类型Article
语种英语
国家Switzerland
英文摘要

Pore condensation and freezing (PCF) is an ice nucleation mechanism that explains ice formation at low ice supersaturation. It assumes that liquid water condenses in pores of solid aerosol particles below water saturation, as described by the Kelvin equation, followed by homogeneous ice nucleation when temperatures are below about 235 K or immersion freezing at higher temperatures, in case the pores contain active sites that induce ice nucleation. Porewater is under tension (negative pressure) below water saturation as described by the Young-Laplace equation. This negative pressure affects the ice nucleation rates and the stability of the pore ice. Here, pressure-dependent parameterizations of classical nucleation theory are developed to quantify the increase in homogeneous ice nucleation rates as a function of tension and to assess the critical diameter of pores that is required to accommodate ice at negative pressures. Growth of ice out of the pore into a macroscopic ice crystal requires ice supersaturation. This supersaturation as a function of the pore opening width is derived, assuming that the ice phase first grows as a spherical cap on top of the pore opening before it starts to expand laterally on the particle surface into a macroscopic ice crystal.


领域地球科学
收录类别SCI-E
WOS记录号WOS:000521140400003
WOS关键词SUPERCOOLED WATER ; CIRRUS CLOUDS ; CRYSTAL NUCLEATION ; AEROSOL-PARTICLES ; SURFACE-TENSION ; HOMOGENEOUS NUCLEATION ; DEPOSITION NUCLEATION ; RADIATIVE PROPERTIES ; LIQUID-WATER ; TEMPERATURE
WOS类目Environmental Sciences ; Meteorology & Atmospheric Sciences
WOS研究方向Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences
引用统计
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/278691
专题地球科学
作者单位ETH, Inst Atmospher & Climate Sci, Zurich, Switzerland
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Marcolli, Claudia. Technical note: Fundamental aspects of ice nucleation via pore condensation and freezing including Laplace pressure and growth into macroscopic ice[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2020,20(5):3209-3230.
APA Marcolli, Claudia.(2020).Technical note: Fundamental aspects of ice nucleation via pore condensation and freezing including Laplace pressure and growth into macroscopic ice.ATMOSPHERIC CHEMISTRY AND PHYSICS,20(5),3209-3230.
MLA Marcolli, Claudia."Technical note: Fundamental aspects of ice nucleation via pore condensation and freezing including Laplace pressure and growth into macroscopic ice".ATMOSPHERIC CHEMISTRY AND PHYSICS 20.5(2020):3209-3230.
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