GSTDTAP  > 气候变化
DOI10.1029/2020GL087036
Spin Transition of Iron in delta-(Al,Fe)OOH Induces Thermal Anomalies in Earth's Lower Mantle
Hsieh, Wen-Pin1,2; Ishii, Takayuki3; Chao, Keng-Hsien1; Tsuchiya, Jun4; Deschamps, Frederic1; Ohtaitu, Eiji5
2020-02-28
发表期刊GEOPHYSICAL RESEARCH LETTERS
ISSN0094-8276
EISSN1944-8007
出版年2020
卷号47期号:4
文章类型Article
语种英语
国家Taiwan; Germany; Japan
英文摘要

Seismic anomalies observed in Earth's deep mantle are conventionally considered to be associated with thermal and compositional anomalies, and possibly partial melt of major lower-mantle phases. However, through deep water cycle, impacts of hydrous minerals on geophysical observables and on the deep mantle thermal state and geodynamics remain poorly understood. Here we precisely measured thermal conductivity of delta-(Al,Fe)OOH, an important water-carrying mineral in Earth's deep interior, to lowermost mantle pressures at room temperature. The thermal conductivity varies drastically by twofold to threefold across the spin transition of iron, resulting in an exceptionally low thermal conductivity at the lowermost mantle conditions. As delta-(Al,Fe)OOH is transported to the lowermost mantle, its exceptionally low thermal conductivity may serve as a local thermal insulator, promoting high-temperature anomalies and the formation of partial melt and thermal plumes at the base of the mantle, strongly influencing thermo-chemical profiles in the region and fate of Earth's deep water cycle.


Plain Language Summary Hydrous minerals subducted to Earth's deep interior may critically affect the thermo-chemical and seismic signatures observed at the bottom of the mantle. We measured thermal conductivity of delta-(Al,Fe)OOH, an important water carrier in deep Earth, to the lowermost mantle pressures. Its thermal conductivity varies drastically across the spin transition of iron and approaches an exceptionally low value of similar to 5 W.m(-1).K-1 at the lowermost mantle conditions, much smaller than the pyrolitic mantle. Such anomalous evolution of thermal conductivity would induce anomalies in heat flux and temperature profile in the lower mantle. It could create a local thermal insulating effect that heats up slab's crust at the lowermost mantle, facilitating dehydration melting of surrounding mantle and affecting thermo-chemical features in the region.


领域气候变化
收录类别SCI-E
WOS记录号WOS:000529120100042
WOS关键词PHASE DELTA-ALOOH ; EQUATION-OF-STATE ; HYDROUS PHASE ; WATER TRANSPORT ; HIGH-PRESSURE ; CONDUCTIVITY ; STABILITY ; GPA ; OLIVINE ; DIFFRACTION
WOS类目Geosciences, Multidisciplinary
WOS研究方向Geology
引用统计
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/279695
专题气候变化
作者单位1.Acad Sinica, Inst Earth Sci, Taipei, Taiwan;
2.Natl Taiwan Univ, Dept Geosci, Taipei, Taiwan;
3.Univ Bayreuth, Bayerisches Geoinst, Bayreuth, Germany;
4.Ehime Univ, Geodynam Res Ctr, Matsuyama, Ehime, Japan;
5.Tohoku Univ, Grad Sch Sci, Dept Earth Sci, Sendai, Miyagi, Japan
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GB/T 7714
Hsieh, Wen-Pin,Ishii, Takayuki,Chao, Keng-Hsien,et al. Spin Transition of Iron in delta-(Al,Fe)OOH Induces Thermal Anomalies in Earth's Lower Mantle[J]. GEOPHYSICAL RESEARCH LETTERS,2020,47(4).
APA Hsieh, Wen-Pin,Ishii, Takayuki,Chao, Keng-Hsien,Tsuchiya, Jun,Deschamps, Frederic,&Ohtaitu, Eiji.(2020).Spin Transition of Iron in delta-(Al,Fe)OOH Induces Thermal Anomalies in Earth's Lower Mantle.GEOPHYSICAL RESEARCH LETTERS,47(4).
MLA Hsieh, Wen-Pin,et al."Spin Transition of Iron in delta-(Al,Fe)OOH Induces Thermal Anomalies in Earth's Lower Mantle".GEOPHYSICAL RESEARCH LETTERS 47.4(2020).
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