Rational synthesis of atomically precise graphene nanoribbons directly on metal oxide surfaces

doi:10.1126/science.abb8880

GSTDTAP > 气候变化

DOI	10.1126/science.abb8880
	Rational synthesis of atomically precise graphene nanoribbons directly on metal oxide surfaces
	Marek Kolmer; Ann-Kristin Steiner; Irena Izydorczyk; Wonhee Ko; Mads Engelund; Marek Szymonski; An-Ping Li; Konstantin Amsharov
	2020-07-31
发表期刊	Science
出版年	2020
英文摘要	Atomically precise nanographenes and nanoribbons have been synthesized on metal surfaces that catalyze cyclode-hydrogenation of precursors. However, for use in devices, these structures usually must be transferred to insulating or semiconducting surfaces. Kolmer et al. synthesized precise graphene nanoribbons on the surface of rutile titanium dioxide (TiO2) that assisted the cyclode-hydrofluorination of specifically designed precursor molecules through a series of thermally triggered transformations. Scanning tunneling microscopy and spectroscopy confirmed the formation of well-defined zigzag ends of the nanoribbons as well as their weak interaction with the substrate. Science , this issue p. [571][1] Atomically precise graphene nanoribbons (GNRs) attract great interest because of their highly tunable electronic, optical, and transport properties. However, on-surface synthesis of GNRs is typically based on metal surface–assisted chemical reactions, where metallic substrates strongly screen their designer electronic properties and limit further applications. Here, we present an on-surface synthesis approach to forming atomically precise GNRs directly on semiconducting metal oxide surfaces. The thermally triggered multistep transformations preprogrammed in our precursors’ design rely on highly selective and sequential activations of carbon-bromine (C-Br) and carbon-fluorine (C-F) bonds and cyclodehydrogenation. The formation of planar armchair GNRs terminated by well-defined zigzag ends is confirmed by scanning tunneling microscopy and spectroscopy, which also reveal weak interaction between GNRs and the rutile titanium dioxide substrate. [1]: /lookup/doi/10.1126/science.abb8880
领域	气候变化 ; 资源环境
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引用统计
文献类型	期刊论文
条目标识符	http://119.78.100.173/C666/handle/2XK7JSWQ/286873
专题	气候变化资源环境科学
推荐引用方式 GB/T 7714	Marek Kolmer,Ann-Kristin Steiner,Irena Izydorczyk,et al. Rational synthesis of atomically precise graphene nanoribbons directly on metal oxide surfaces[J]. Science,2020.
APA	Marek Kolmer.,Ann-Kristin Steiner.,Irena Izydorczyk.,Wonhee Ko.,Mads Engelund.,...&Konstantin Amsharov.(2020).Rational synthesis of atomically precise graphene nanoribbons directly on metal oxide surfaces.Science.
MLA	Marek Kolmer,et al."Rational synthesis of atomically precise graphene nanoribbons directly on metal oxide surfaces".Science (2020).