GSTDTAP  > 地球科学
DOI10.5194/acp-13-9731-2013
Naphthalene SOA: redox activity and naphthoquinone gas–particle partitioning
R. D. McWhinney, S. Zhou, and J. P. D. Abbatt
2013-10-02
发表期刊Atmospheric Chemistry and Physics
出版年2013
英文摘要Chamber secondary organic aerosol (SOA) from low-NOx photooxidation of naphthalene by hydroxyl radical was examined with respect to its redox cycling behaviour using the dithiothreitol (DTT) assay. Naphthalene SOA was highly redox-active, consuming DTT at an average rate of 118 ± 14 pmol per minute per μg of SOA material. Measured particle-phase masses of the major previously identified redox active products, 1,2- and 1,4-naphthoquinone, accounted for only 21 ± 3% of the observed redox cycling activity. The redox-active 5-hydroxy-1,4-naphthoquinone was identified as a new minor product of naphthalene oxidation, and including this species in redox activity predictions increased the predicted DTT reactivity to 30 ± 5% of observations. These results suggest that there are substantial unidentified redox-active SOA constituents beyond the small quinones that may be important toxic components of these particles. A gas-to-SOA particle partitioning coefficient was calculated to be (7.0 ± 2.5) × 10−4 m3 μg−1 for 1,4-naphthoquinone at 25 °C. This value suggests that under typical warm conditions, 1,4-naphthoquinone is unlikely to contribute strongly to redox behaviour of ambient particles, although further work is needed to determine the potential impact under conditions such as low temperatures where partitioning to the particle is more favourable. Also, higher order oxidation products that likely account for a substantial fraction of the redox cycling capability of the naphthalene SOA are likely to partition much more strongly to the particle phase.

领域地球科学
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文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/288022
专题地球科学
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R. D. McWhinney, S. Zhou, and J. P. D. Abbatt. Naphthalene SOA: redox activity and naphthoquinone gas–particle partitioning[J]. Atmospheric Chemistry and Physics,2013.
APA R. D. McWhinney, S. Zhou, and J. P. D. Abbatt.(2013).Naphthalene SOA: redox activity and naphthoquinone gas–particle partitioning.Atmospheric Chemistry and Physics.
MLA R. D. McWhinney, S. Zhou, and J. P. D. Abbatt."Naphthalene SOA: redox activity and naphthoquinone gas–particle partitioning".Atmospheric Chemistry and Physics (2013).
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