GSTDTAP  > 地球科学
DOI10.5194/acp-13-7405-2013
ACE-FTS observations of acetonitrile in the lower stratosphere
J. J. Harrison and P. F. Bernath
2013-08-02
发表期刊Atmospheric Chemistry and Physics
出版年2013
英文摘要This work reports the first infrared satellite remote-sensing measurements of acetonitrile (CH3CN) in the Earth's atmosphere using solar occultation measurements made by the Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) between 2004 and 2011. The retrieval scheme uses new quantitative laboratory spectroscopic measurements of acetonitrile (Harrison and Bernath, 2012). Although individual ACE-FTS profile measurements are dominated by measurement noise, median profiles in 10° latitude bins show a steady decline in volume mixing ratio from ~150 ppt (parts per trillion) at 11.5 km to < 40 ppt at 25.5–29.5 km. These new measurements agree well with the scant available air- and balloon-borne data in the lower stratosphere. An acetonitrile stratospheric lifetime of 73 ± 20 yr has been determined.

领域地球科学
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文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/288034
专题地球科学
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J. J. Harrison and P. F. Bernath. ACE-FTS observations of acetonitrile in the lower stratosphere[J]. Atmospheric Chemistry and Physics,2013.
APA J. J. Harrison and P. F. Bernath.(2013).ACE-FTS observations of acetonitrile in the lower stratosphere.Atmospheric Chemistry and Physics.
MLA J. J. Harrison and P. F. Bernath."ACE-FTS observations of acetonitrile in the lower stratosphere".Atmospheric Chemistry and Physics (2013).
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