GSTDTAP  > 地球科学
DOI10.1016/j.atmosres.2020.104905
Effect of organic coatings derived from the OH-initiated oxidation of amines on soot morphology and cloud activation
Chen, Chao1,2; Enekwizu, Ogochukwu Y.3; Ma, Xin2; Jiang, Youling2; Khalizov, Alexei F.3,4; Zheng, Jun2; Ma, Yan2
2020-07-15
发表期刊ATMOSPHERIC RESEARCH
ISSN0169-8095
EISSN1873-2895
出版年2020
卷号239
文章类型Article
语种英语
国家Peoples R China; USA
英文摘要

The presence of coatings on soot particles may significantly influence their environmental impacts. In this study, the processing of soot by OH-initiated photooxidation of amines was investigated in a series of chamber experiments. Monodisperse soot aerosol was exposed to oxidation products of monoethanolamine (MEA), triethylamine (TEA) and aniline, and changes in particle size, mass, effective density, shape factor, and activation as cloud condensation nuclei (CCN) were simultaneously measured by a suite of instruments. Different initial concentrations of amine precursor were applied, and in selected experiments, organic coatings were removed by thermal denuding to investigate the change of the soot core structure. Aniline generated the largest amount of low volatility condensable oxidation products, which induced minimal soot restructuring even at a high aniline concentration. On the contrary, the high volatility of MEA oxidation products led to reversible condensation on soot while inducing significant aggregate collapse for a smaller coating mass than with aniline. The products from TEA photooxidation showed volatility intermediate between aniline and MEA and induced the most significant restructuring. It can be concluded that restructuring depended on the physical state of the coating material and its distribution over the aggregate surface. Soot aged with the three different amine precursors produced distinct CCN activity profiles that depended on measured coating mass, and there was an indication that intermediate volatility oxidation products of MEA co-condensed with water during the droplet activation process.


英文关键词Soot Amine Photochemical aging Restructuring CCN
领域地球科学
收录类别SCI-E
WOS记录号WOS:000525324000016
WOS关键词AERODYNAMIC DIAMETER MEASUREMENTS ; SECONDARY AEROSOL FORMATION ; BLACK-CARBON ; DENSITY CHARACTERIZATION ; HETEROGENEOUS REACTIONS ; ATMOSPHERIC CHEMISTRY ; PARTICLE MORPHOLOGY ; COMBINED MOBILITY ; LIGHT-ABSORPTION ; SMOG CHAMBER
WOS类目Meteorology & Atmospheric Sciences
WOS研究方向Meteorology & Atmospheric Sciences
引用统计
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/289284
专题地球科学
作者单位1.Chengdu Univ Informat Technol, Coll Resources & Environm, Chengdu 610225, Sichuan, Peoples R China;
2.Nanjing Univ Informat Sci & Technol, Collaborat Innovat Ctr Atmospher Environm & Equip, Nanjing 210044, Peoples R China;
3.New Jersey Inst Technol, Dept Chem & Mat Engn, Newark, NJ 07102 USA;
4.New Jersey Inst Technol, Dept Chem & Environm Sci, Newark, NJ 07102 USA
推荐引用方式
GB/T 7714
Chen, Chao,Enekwizu, Ogochukwu Y.,Ma, Xin,et al. Effect of organic coatings derived from the OH-initiated oxidation of amines on soot morphology and cloud activation[J]. ATMOSPHERIC RESEARCH,2020,239.
APA Chen, Chao.,Enekwizu, Ogochukwu Y..,Ma, Xin.,Jiang, Youling.,Khalizov, Alexei F..,...&Ma, Yan.(2020).Effect of organic coatings derived from the OH-initiated oxidation of amines on soot morphology and cloud activation.ATMOSPHERIC RESEARCH,239.
MLA Chen, Chao,et al."Effect of organic coatings derived from the OH-initiated oxidation of amines on soot morphology and cloud activation".ATMOSPHERIC RESEARCH 239(2020).
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Chen, Chao]的文章
[Enekwizu, Ogochukwu Y.]的文章
[Ma, Xin]的文章
百度学术
百度学术中相似的文章
[Chen, Chao]的文章
[Enekwizu, Ogochukwu Y.]的文章
[Ma, Xin]的文章
必应学术
必应学术中相似的文章
[Chen, Chao]的文章
[Enekwizu, Ogochukwu Y.]的文章
[Ma, Xin]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。