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DOI | 10.1038/s41893-019-0452-6 |
Magnetite nanoparticles as efficient materials for removal of glyphosate from water | |
Park, Hyoungwon1; May, Alexander1; Portilla, Luis1; Dietrich, Hanno2,3; Muench, Friedrich4; Rejek, Tobias1; Sarcletti, Marco1; Banspach, Leena4; Zahn, Dirk2,3; Halik, Marcus1 | |
2020-02-01 | |
发表期刊 | NATURE SUSTAINABILITY
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ISSN | 2398-9629 |
出版年 | 2020 |
卷号 | 3期号:2页码:129-+ |
文章类型 | Article |
语种 | 英语 |
国家 | Germany |
英文摘要 | Concentrations of glyphosate, a common herbicide, in water can be problematic due to its toxicity. Using both artificial and real water samples, this study shows the sustainability advantages of using magnetite (Fe3O4) nanoparticles to remove glyphosate from water. Glyphosate is one of the most commonly used herbicides, but, due to its suspected toxicity, it is simultaneously the most disputed one. Its worldwide application in huge quantities may lead to water concentrations that locally exceed statutory contamination levels. Therefore, a simple toolkit is required to remove glyphosate and its major metabolite from water. Here we show a method for the magnetic remediation of glyphosate from artificial and real water samples to below the maximum permissible value or even below the analytical detection limit. The chemical structure of glyphosate enables fast and stable covalent binding on the surface of magnetite (Fe3O4) nanoparticles, which act as catchers and carriers for magnetic removal. The small size of the nanoparticles (~20 nm diameter) provides a large active area. The glyphosate binding was analysed by infrared spectroscopy, thermogravimetric analysis and dynamic light scattering, while the remediation was investigated by liquid chromatography-mass spectrometry. Results from molecular dynamics simulations support the proposed binding mechanism. The combination of efficient remediation with inexpensive and recyclable magnetite nanoparticles suggests a simple method for the sustainable removal of glyphosate, and the concept may lead to a general approach to eliminate this class of organophosphorus compounds from water. |
领域 | 资源环境 |
收录类别 | SCI-E ; SSCI |
WOS记录号 | WOS:000513353400012 |
WOS关键词 | IMPLEMENTING MOLECULAR-DYNAMICS ; SELF-ASSEMBLED MONOLAYERS ; CORE-SHELL NANOPARTICLES ; AMINOMETHYLPHOSPHONIC ACID ; PHOSPHONIC ACID ; IRON-OXIDE ; SURFACE BINDING ; ALUMINUM-OXIDE ; DIELECTRICS ; MODEL |
WOS类目 | Green & Sustainable Science & Technology ; Environmental Sciences ; Environmental Studies |
WOS研究方向 | Science & Technology - Other Topics ; Environmental Sciences & Ecology |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/289928 |
专题 | 资源环境科学 |
作者单位 | 1.Friedrich Alexander Univ Erlangen Nurnberg FAU, Dept Mat Sci Organ Mat & Devices OMD, Erlangen, Germany; 2.Friedrich Alexander Univ Erlangen Nurnberg FAU, Comp Chem Ctr, Erlangen, Germany; 3.Friedrich Alexander Univ Erlangen Nurnberg FAU, Interdisciplinary Ctr Mol Mat, Erlangen, Germany; 4.Bayer Landesamt Gesundheit & Lebensmittelsicherhe, Erlangen, Germany |
推荐引用方式 GB/T 7714 | Park, Hyoungwon,May, Alexander,Portilla, Luis,et al. Magnetite nanoparticles as efficient materials for removal of glyphosate from water[J]. NATURE SUSTAINABILITY,2020,3(2):129-+. |
APA | Park, Hyoungwon.,May, Alexander.,Portilla, Luis.,Dietrich, Hanno.,Muench, Friedrich.,...&Halik, Marcus.(2020).Magnetite nanoparticles as efficient materials for removal of glyphosate from water.NATURE SUSTAINABILITY,3(2),129-+. |
MLA | Park, Hyoungwon,et al."Magnetite nanoparticles as efficient materials for removal of glyphosate from water".NATURE SUSTAINABILITY 3.2(2020):129-+. |
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