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DOI | 10.1002/2016JD025619 |
Laboratory observations of temperature and humidity dependencies of nucleation and growth rates of sub-3nm particles | |
Yu, Huan1; Dai, Liang1; Zhao, Yi1; Kanawade, Vijay P.2; Tripathi, Sachchida N.3,4; Ge, Xinlei1; Chen, Mindong1; Lee, Shan-Hu5 | |
2017-02-16 | |
发表期刊 | JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
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ISSN | 2169-897X |
EISSN | 2169-8996 |
出版年 | 2017 |
卷号 | 122期号:3 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China; India; USA |
英文摘要 | Temperature and relative humidity (RH) are the most important thermodynamic parameters in aerosol formation, yet laboratory studies of nucleation and growth dependencies on temperature and RH are lacking. Here we report the experimentally observed temperature and RH dependences of sulfuric acid aerosol nucleation and growth. Experiments were performed in a flow tube in the temperature range from 248 to 313 K, RH from 0.8% to 79%, and relative acidity (RA) of sulfuric acid from 6 x 10(-5) to 0.38 (2 x 10(7)-10(9) cm(-3)). The impurity levels of base compounds were determined to be NH3 < 23 pptv (parts per thousand by volume), methylamine < 1.5 pptv, and dimethylamine < 0.52 pptv. Our results showed that low temperatures favor nucleation at fixed sulfuric acid concentration but impede nucleation when RA is fixed. It is also shown that binary nucleation of sulfuric acid and water is negligible in planetary boundary layer temperature and sulfuric acid ranges. An empirical algorithm was derived to correlate the nucleation rate with RA, RH, and temperature together. Collision-limited condensation of free-sulfuric acid molecules fails to predict the observed growth rate in the sub-3nm size range, as well as its dependence on temperature and RH. This suggests that evaporation, sulfuric acid hydration, and possible involvement of other ternary molecules should be considered for the sub-3nm particle growth. |
领域 | 气候变化 |
收录类别 | SCI-E |
WOS记录号 | WOS:000396119200032 |
WOS关键词 | SULFURIC-ACID-WATER ; ATMOSPHERIC PARTICLES ; SIZE DISTRIBUTION ; AEROSOL ; NANOPARTICLES ; AMMONIA ; H2SO4 ; IONS |
WOS类目 | Meteorology & Atmospheric Sciences |
WOS研究方向 | Meteorology & Atmospheric Sciences |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/33007 |
专题 | 气候变化 |
作者单位 | 1.Nanjing Univ Informat Sci & Technol, Sch Environm Sci & Engn, Nanjing, Jiangsu, Peoples R China; 2.Univ Hyderabad, Univ Ctr Earth & Space Sci, Hyderabad, Andhra Pradesh, India; 3.Indian Inst Technol Kanpur, Ctr Environm Sci & Engn, Kanpur, Uttar Pradesh, India; 4.Indian Inst Technol Kanpur, Dept Civil Engn, Kanpur, Uttar Pradesh, India; 5.Univ Alabama, Dept Atmospher Sci, Huntsville, AL 35899 USA |
推荐引用方式 GB/T 7714 | Yu, Huan,Dai, Liang,Zhao, Yi,et al. Laboratory observations of temperature and humidity dependencies of nucleation and growth rates of sub-3nm particles[J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,2017,122(3). |
APA | Yu, Huan.,Dai, Liang.,Zhao, Yi.,Kanawade, Vijay P..,Tripathi, Sachchida N..,...&Lee, Shan-Hu.(2017).Laboratory observations of temperature and humidity dependencies of nucleation and growth rates of sub-3nm particles.JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,122(3). |
MLA | Yu, Huan,et al."Laboratory observations of temperature and humidity dependencies of nucleation and growth rates of sub-3nm particles".JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 122.3(2017). |
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