GSTDTAP  > 气候变化
DOI10.1002/2016JD025619
Laboratory observations of temperature and humidity dependencies of nucleation and growth rates of sub-3nm particles
Yu, Huan1; Dai, Liang1; Zhao, Yi1; Kanawade, Vijay P.2; Tripathi, Sachchida N.3,4; Ge, Xinlei1; Chen, Mindong1; Lee, Shan-Hu5
2017-02-16
发表期刊JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
ISSN2169-897X
EISSN2169-8996
出版年2017
卷号122期号:3
文章类型Article
语种英语
国家Peoples R China; India; USA
英文摘要

Temperature and relative humidity (RH) are the most important thermodynamic parameters in aerosol formation, yet laboratory studies of nucleation and growth dependencies on temperature and RH are lacking. Here we report the experimentally observed temperature and RH dependences of sulfuric acid aerosol nucleation and growth. Experiments were performed in a flow tube in the temperature range from 248 to 313 K, RH from 0.8% to 79%, and relative acidity (RA) of sulfuric acid from 6 x 10(-5) to 0.38 (2 x 10(7)-10(9) cm(-3)). The impurity levels of base compounds were determined to be NH3 < 23 pptv (parts per thousand by volume), methylamine < 1.5 pptv, and dimethylamine < 0.52 pptv. Our results showed that low temperatures favor nucleation at fixed sulfuric acid concentration but impede nucleation when RA is fixed. It is also shown that binary nucleation of sulfuric acid and water is negligible in planetary boundary layer temperature and sulfuric acid ranges. An empirical algorithm was derived to correlate the nucleation rate with RA, RH, and temperature together. Collision-limited condensation of free-sulfuric acid molecules fails to predict the observed growth rate in the sub-3nm size range, as well as its dependence on temperature and RH. This suggests that evaporation, sulfuric acid hydration, and possible involvement of other ternary molecules should be considered for the sub-3nm particle growth.


领域气候变化
收录类别SCI-E
WOS记录号WOS:000396119200032
WOS关键词SULFURIC-ACID-WATER ; ATMOSPHERIC PARTICLES ; SIZE DISTRIBUTION ; AEROSOL ; NANOPARTICLES ; AMMONIA ; H2SO4 ; IONS
WOS类目Meteorology & Atmospheric Sciences
WOS研究方向Meteorology & Atmospheric Sciences
引用统计
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/33007
专题气候变化
作者单位1.Nanjing Univ Informat Sci & Technol, Sch Environm Sci & Engn, Nanjing, Jiangsu, Peoples R China;
2.Univ Hyderabad, Univ Ctr Earth & Space Sci, Hyderabad, Andhra Pradesh, India;
3.Indian Inst Technol Kanpur, Ctr Environm Sci & Engn, Kanpur, Uttar Pradesh, India;
4.Indian Inst Technol Kanpur, Dept Civil Engn, Kanpur, Uttar Pradesh, India;
5.Univ Alabama, Dept Atmospher Sci, Huntsville, AL 35899 USA
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GB/T 7714
Yu, Huan,Dai, Liang,Zhao, Yi,et al. Laboratory observations of temperature and humidity dependencies of nucleation and growth rates of sub-3nm particles[J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,2017,122(3).
APA Yu, Huan.,Dai, Liang.,Zhao, Yi.,Kanawade, Vijay P..,Tripathi, Sachchida N..,...&Lee, Shan-Hu.(2017).Laboratory observations of temperature and humidity dependencies of nucleation and growth rates of sub-3nm particles.JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,122(3).
MLA Yu, Huan,et al."Laboratory observations of temperature and humidity dependencies of nucleation and growth rates of sub-3nm particles".JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 122.3(2017).
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