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Synchrotron infrared spectroscopic evidence of the probable transition to metal hydrogen 期刊论文
NATURE, 2020, 577 (7792) : 631-+
作者:  Zhuang, Zhe;  Yu, Jin-Quan
收藏  |  浏览/下载:25/0  |  提交时间:2020/07/03

Hydrogen has been an essential element in the development of atomic, molecular and condensed matter physics(1). It is predicted that hydrogen should have a metal state(2)  however, understanding the properties of dense hydrogen has been more complex than originally thought, because under extreme conditions the electrons and protons are strongly coupled to each other and ultimately must both be treated as quantum particles(3,4). Therefore, how and when molecular solid hydrogen may transform into a metal is an open question. Although the quest for metal hydrogen has pushed major developments in modern experimental high-pressure physics, the various claims of its observation remain unconfirmed(5-7). Here a discontinuous change of the direct bandgap of hydrogen, from 0.6 electronvolts to below 0.1 electronvolts, is observed near 425 gigapascals. This result is most probably associated with the formation of the metallic state because the nucleus zero-point energy is larger than this lowest bandgap value. Pressures above 400 gigapascals are achieved with the recently developed toroidal diamond anvil cell(8), and the structural changes and electronic properties of dense solid hydrogen at 80 kelvin are probed using synchrotron infrared absorption spectroscopy. The continuous downward shifts of the vibron wavenumber and the direct bandgap with increased pressure point to the stability of phase-III hydrogen up to 425 gigapascals. The present data suggest that metallization of hydrogen proceeds within the molecular solid, in good agreement with previous calculations that capture many-body electronic correlations(9).


  
Dualities and non-Abelian mechanics 期刊论文
NATURE, 2020, 577 (7792) : 636-+
作者:  Song, Xinyang;  Sun, Ximei;  Oh, Sungwhan F.;  Wu, Meng;  Zhang, Yanbo;  Zheng, Wen;  Geva-Zatorsky, Naama;  Jupp, Ray;  Mathis, Diane;  Benoist, Christophe;  Kasper, Dennis L.
收藏  |  浏览/下载:13/0  |  提交时间:2020/07/03

Dualities-mathematical mappings between different systems-can act as hidden symmetries that enable materials design beyond that suggested by crystallographic space groups.


Dualities are mathematical mappings that reveal links between apparently unrelated systems in virtually every branch of physics(1-8). Systems mapped onto themselves by a duality transformation are called self-dual and exhibit remarkable properties, as exemplified by the scale invariance of an Ising magnet at the critical point. Here we show how dualities can enhance the symmetries of a dynamical matrix (or Hamiltonian), enabling the design of metamaterials with emergent properties that escape a standard group theory analysis. As an illustration, we consider twisted kagome lattices(9-15), reconfigurable mechanical structures that change shape by means of a collapse mechanism(9). We observe that pairs of distinct configurations along the mechanism exhibit the same vibrational spectrum and related elastic moduli. We show that these puzzling properties arise from a duality between pairs of configurations on either side of a mechanical critical point. The critical point corresponds to a self-dual structure with isotropic elasticity even in the absence of spatial symmetries and a twofold-degenerate spectrum over the entire Brillouin zone. The spectral degeneracy originates from a version of Kramers'  theorem(16,17) in which fermionic time-reversal invariance is replaced by a hidden symmetry emerging at the self-dual point. The normal modes of the self-dual systems exhibit non-Abelian geometric phases(18,19) that affect the semiclassical propagation of wavepackets(20), leading to non-commuting mechanical responses. Our results hold promise for holonomic computation(21) and mechanical spintronics by allowing on-the-fly manipulation of synthetic spins carried by phonons.


  
Warming and oligotrophication cause shifts in freshwater phytoplankton communities 期刊论文
GLOBAL CHANGE BIOLOGY, 2018, 24 (10) : 4532-4543
作者:  Verbeek, Laura;  Gall, Andrea;  Hillebrand, Helmut;  Striebel, Maren
收藏  |  浏览/下载:7/0  |  提交时间:2019/04/09
biodiversity  climate change  evenness  oligotrophication  Planktotrons  regime shift  species richness  temperature increase  tipping point  warming  
Avoiding a crisis of motivation for ocean management under global environmental change 期刊论文
GLOBAL CHANGE BIOLOGY, 2017, 23 (11)
作者:  Mumby, Peter J.;  Sanchirico, James N.;  Broad, Kenneth;  Beck, Michael W.;  Tyedmers, Peter;  Morikawa, Megan;  Okey, Thomas A.;  Crowder, Larry B.;  Fulton, Elizabeth A.;  Kelso, Denny;  Kleypas, Joanie A.;  Munch, Stephan B.;  Glynn, Polita;  Matthews, Kathryn;  Lubchenco, Jane
收藏  |  浏览/下载:11/0  |  提交时间:2019/04/09
Arctic  climate change  coral reefs  fisheries  resilience  tipping point  
Changes in vegetation phenology are not reflected in atmospheric CO2 and C-13/C-12 seasonality 期刊论文
GLOBAL CHANGE BIOLOGY, 2017, 23 (10)
作者:  Gonsamo, Alemu;  39;Odorico, Petra
收藏  |  浏览/下载:6/0  |  提交时间:2019/04/09
Alert station  carbon isotope  climate change  CO2 seasonality  La Jolla station  Mauna Loa Observatory  phenology  Point Barrow station  soil respiration  delta C-13  
Threshold loss of discontinuous permafrost and landscape evolution 期刊论文
GLOBAL CHANGE BIOLOGY, 2017, 23 (7)
作者:  Chasmer, Laura;  Hopkinson, Chris
收藏  |  浏览/下载:4/0  |  提交时间:2019/04/09
boreal  climate change  ENSO  hydrology  light detection and ranging  permafrost  remote sensing  tipping point  
Population trends influence species ability to track climate change 期刊论文
GLOBAL CHANGE BIOLOGY, 2017, 23 (4)
作者:  Ralston, Joel;  Deluca, William V.;  Feldman, Richard E.;  King, David I.
收藏  |  浏览/下载:6/0  |  提交时间:2019/04/09
birds  Breeding Bird Survey  change-point analysis  climate niche  Grinellian niche