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Dualities and non-Abelian mechanics 期刊论文
NATURE, 2020, 577 (7792) : 636-+
作者:  Song, Xinyang;  Sun, Ximei;  Oh, Sungwhan F.;  Wu, Meng;  Zhang, Yanbo;  Zheng, Wen;  Geva-Zatorsky, Naama;  Jupp, Ray;  Mathis, Diane;  Benoist, Christophe;  Kasper, Dennis L.
收藏  |  浏览/下载:28/0  |  提交时间:2020/07/03

Dualities-mathematical mappings between different systems-can act as hidden symmetries that enable materials design beyond that suggested by crystallographic space groups.


Dualities are mathematical mappings that reveal links between apparently unrelated systems in virtually every branch of physics(1-8). Systems mapped onto themselves by a duality transformation are called self-dual and exhibit remarkable properties, as exemplified by the scale invariance of an Ising magnet at the critical point. Here we show how dualities can enhance the symmetries of a dynamical matrix (or Hamiltonian), enabling the design of metamaterials with emergent properties that escape a standard group theory analysis. As an illustration, we consider twisted kagome lattices(9-15), reconfigurable mechanical structures that change shape by means of a collapse mechanism(9). We observe that pairs of distinct configurations along the mechanism exhibit the same vibrational spectrum and related elastic moduli. We show that these puzzling properties arise from a duality between pairs of configurations on either side of a mechanical critical point. The critical point corresponds to a self-dual structure with isotropic elasticity even in the absence of spatial symmetries and a twofold-degenerate spectrum over the entire Brillouin zone. The spectral degeneracy originates from a version of Kramers'  theorem(16,17) in which fermionic time-reversal invariance is replaced by a hidden symmetry emerging at the self-dual point. The normal modes of the self-dual systems exhibit non-Abelian geometric phases(18,19) that affect the semiclassical propagation of wavepackets(20), leading to non-commuting mechanical responses. Our results hold promise for holonomic computation(21) and mechanical spintronics by allowing on-the-fly manipulation of synthetic spins carried by phonons.


  
Constructing protein polyhedra via orthogonal chemical interactions 期刊论文
NATURE, 2020, 578 (7793) : 172-+
作者:  Mooley, K. P.;  Deller, A. T.;  Gottlieb, O.;  Nakar, E.;  Hallinan, G.;  Bourke, S.;  Frail, D. A.;  Horesh, A.;  Corsi, A.;  Hotokezaka, K.
收藏  |  浏览/下载:19/0  |  提交时间:2020/07/03

Many proteins exist naturally as symmetrical homooligomers or homopolymers(1). The emergent structural and functional properties of such protein assemblies have inspired extensive efforts in biomolecular design(2-5). As synthesized by ribosomes, proteins are inherently asymmetric. Thus, they must acquire multiple surface patches that selectively associate to generate the different symmetry elements needed to form higher-order architectures(1,6)-a daunting task for protein design. Here we address this problem using an inorganic chemical approach, whereby multiple modes of protein-protein interactions and symmetry are simultaneously achieved by selective, '  one-pot'  coordination of soft and hard metal ions. We show that a monomeric protein (protomer) appropriately modified with biologically inspired hydroxamate groups and zinc-binding motifs assembles through concurrent Fe3+ and Zn2+ coordination into discrete dodecameric and hexameric cages. Our cages closely resemble natural polyhedral protein architectures(7,8) and are, to our knowledge, unique among designed systems(9-13) in that they possess tightly packed shells devoid of large apertures. At the same time, they can assemble and disassemble in response to diverse stimuli, owing to their heterobimetallic construction on minimal interprotein-bonding footprints. With stoichiometries ranging from [2 Fe:9 Zn:6 protomers] to [8 Fe:21 Zn:12 protomers], these protein cages represent some of the compositionally most complex protein assemblies-or inorganic coordination complexes-obtained by design.


An inorganic chemical approach to biomolecular design is used to generate '  cages'  that can simultaneously promote symmetry and multiple modes of protein interactions.


  
Cumulative biomass curves describe past and present conditions of Large Marine Ecosystems 期刊论文
GLOBAL CHANGE BIOLOGY, 2019
作者:  Pranovi, Fabio;  Libralato, Simone;  Zucchetta, Matteo;  Monti, Marco Anelli;  Link, Jason S.
收藏  |  浏览/下载:17/0  |  提交时间:2019/11/27
cumulative biomass  Ecosystem Approach  ecosystem indicators  emergent properties  trophic level  
Assessing the Catchment Storage Function Through a Dual-Storage Concept 期刊论文
WATER RESOURCES RESEARCH, 2019, 55 (1) : 476-494
作者:  Carrer, Gwenael E.;  Klaus, Julian;  Pfister, Laurent
收藏  |  浏览/下载:13/0  |  提交时间:2019/04/09
connectivity  storage  water balance  recession analysis  catchment  emergent properties  
Aquatic Carbon-Nutrient Dynamics as Emergent Properties of Hydrological, Biogeochemical, and Ecological Interactions: Scientific Advances 期刊论文
WATER RESOURCES RESEARCH, 2018, 54 (10) : 7138-7142
作者:  Covino, Tim;  Golden, Heather E.;  Li, Hong-Yi;  Tang, Jinyun
收藏  |  浏览/下载:14/0  |  提交时间:2019/04/09
Aquatic ecosystems  Emergent properties  Nutrients  Carbon  Hydro-biogeochemical interactions  
Changes in structural heterogeneity and stand productivity by mixing Scots pine and Maritime pine 期刊论文
FOREST ECOLOGY AND MANAGEMENT, 2017, 405
作者:  Riofrio, Jose;  del Rio, Miren;  Pretzsch, Hans;  Bravo, Felipe
收藏  |  浏览/下载:19/0  |  提交时间:2019/04/09
Mixing effects  Over-yielding  Stand structure  Tree allometry  Emergent properties  Vertical stratification