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科学家优化利用太阳能将CO2转化为CO的反应机理 快报文章
气候变化快报,2022年第05期
作者:  秦冰雪
Microsoft Word(15Kb)  |  收藏  |  浏览/下载:759/0  |  提交时间:2022/03/04
Spectrum  Carbon Dioxide Conversion  Covalent Organic Frameworks  
新型催化剂可以在水中或高温下实现CO2转化 快报文章
气候变化快报,2022年第02期
作者:  秦冰雪
Microsoft Word(15Kb)  |  收藏  |  浏览/下载:771/0  |  提交时间:2022/01/19
Climate Change  Metal-organic Frameworks  CO2 Conversion  
Potential for large-scale CO2 removal via enhanced rock weathering with croplands 期刊论文
NATURE, 2020, 583 (7815) : 242-+
作者:  David J. Beerling;  Euripides P. Kantzas;  Mark R. Lomas;  Peter Wade;  Rafael M. Eufrasio;  Phil Renforth;  Binoy Sarkar;  M. Grace Andrews;  Rachael H. James;  Christopher R. Pearce;  Jean-Francois Mercure;  Hector Pollitt;  Philip B. Holden;  Neil R. Edwards;  Madhu Khanna;  Lenny Koh;  Shaun Quegan;  Nick F. Pidgeon;  Ivan A. Janssens;  James Hansen;  Steven A. Banwart
收藏  |  浏览/下载:56/0  |  提交时间:2020/07/14

Enhanced silicate rock weathering (ERW), deployable with croplands, has potential use for atmospheric carbon dioxide (CO2) removal (CDR), which is now necessary to mitigate anthropogenic climate change(1). ERW also has possible co-benefits for improved food and soil security, and reduced ocean acidification(2-4). Here we use an integrated performance modelling approach to make an initial techno-economic assessment for 2050, quantifying how CDR potential and costs vary among nations in relation to business-as-usual energy policies and policies consistent with limiting future warming to 2 degrees Celsius(5). China, India, the USA and Brazil have great potential to help achieve average global CDR goals of 0.5 to 2gigatonnes of carbon dioxide (CO2) per year with extraction costs of approximately US$80-180 per tonne of CO2. These goals and costs are robust, regardless of future energy policies. Deployment within existing croplands offers opportunities to align agriculture and climate policy. However, success will depend upon overcoming political and social inertia to develop regulatory and incentive frameworks. We discuss the challenges and opportunities of ERW deployment, including the potential for excess industrial silicate materials (basalt mine overburden, concrete, and iron and steel slag) to obviate the need for new mining, as well as uncertainties in soil weathering rates and land-ocean transfer of weathered products.


  
Single-chain heteropolymers transport protons selectively and rapidly 期刊论文
NATURE, 2020, 577 (7789) : 216-+
作者:  Jiang, Tao;  Hall, Aaron;  Eres, Marco;  Hemmatian, Zahra;  Qiao, Baofu;  Zhou, Yun;  Ruan, Zhiyuan;  Couse, Andrew D.;  Heller, William T.;  Huang, Haiyan;  de la Cruz, Monica Olvera;  Rolandi, Marco;  Xu, Ting
收藏  |  浏览/下载:18/0  |  提交时间:2020/07/03

Precise protein sequencing and folding are believed to generate the structure and chemical diversity of natural channels(1,2), both of which are essential to synthetically achieve proton transport performance comparable to that seen in natural systems. Geometrically defined channels have been fabricated using peptides, DNAs, carbon nanotubes, sequence-defined polymers and organic frameworks(3-13). However, none of these channels rivals the performance observed in their natural counterparts. Here we show that without forming an atomically structured channel, four-monomer-based random heteropolymers (RHPs)(14) can mimic membrane proteins and exhibit selective proton transport across lipid bilayers at a rate similar to those of natural proton channels. Statistical control over the monomer distribution in an RHP leads to segmental heterogeneity in hydrophobicity, which facilitates the insertion of single RHPs into the lipid bilayers. It also results in bilayer-spanning segments containing polar monomers that promote the formation of hydrogen-bonded chains(15,16) for proton transport. Our study demonstrates the importance of the adaptability that is enabled by statistical similarity among RHP chains and of the modularity provided by the chemical diversity of monomers, to achieve uniform behaviour in heterogeneous systems. Our results also validate statistical randomness as an unexplored approach to realize protein-like behaviour at the single-polymer-chain level in a predictable manner.


  
Legacy, Rather Than Adequacy, Drives the Selection of Hydrological Models 期刊论文
WATER RESOURCES RESEARCH, 2019, 55 (1) : 378-390
作者:  Addor, N.;  Melsen, L. A.
收藏  |  浏览/下载:14/0  |  提交时间:2019/04/09
model selection  model evaluation  bibliometric study  text mining  community model  modular modeling frameworks  
Transition Towards a Resource Efficient Circular Economy in Europe: Policy Lessons From the EU and the Member States 期刊论文
ECOLOGICAL ECONOMICS, 2019, 155: 7-19
作者:  Domenech, Teresa;  Bahn-Walkowiak, Bettina
收藏  |  浏览/下载:9/0  |  提交时间:2019/04/09
Resource efficiency  Circular economy  Policy frameworks  Policy mixes  Resource policy  System of economic incentives  
Rethinking urban green infrastructure and ecosystem services from the perspective of sub-Saharan African cities 期刊论文
LANDSCAPE AND URBAN PLANNING, 2018, 180: 328-338
作者:  Lindley, Sarah;  Pauleit, Stephan;  Yeshitela, Kumelachew;  Cilliers, Sarel;  Shackleton, Charlie
收藏  |  浏览/下载:9/0  |  提交时间:2019/04/09
Green infrastructure  Ecosystem benefits  Urban settlements  Frameworks  Review  Africa  
Discourses in Ecosystem Accounting: A Survey of the Expert Community 期刊论文
ECOLOGICAL ECONOMICS, 2018, 144: 82-99
作者:  Bordt, Michael
收藏  |  浏览/下载:12/0  |  提交时间:2019/04/09
Classification  Convergence  Critical Natural Capital  Environmental Accounting  Environmental Policy  Frameworks