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Observations of grain-boundary phase transformations in an elemental metal 期刊论文
NATURE, 2020, 579 (7799) : 375-+
作者:  Valente, Luis;  Phillimore, Albert B.;  Melo, Martim;  Warren, Ben H.;  Clegg, Sonya M.;  Havenstein, Katja;  Tiedemann, Ralph;  Illera, Juan Carlos;  Thebaud, Christophe;  Aschenbach, Tina;  Etienne, Rampal S.
收藏  |  浏览/下载:28/0  |  提交时间:2020/07/03

Atomic-resolution observations combined with simulations show that grain boundaries within elemental copper undergo temperature-induced solid-state phase transformation to different structures  grain boundary phases can also coexist and are kinetically trapped structures.


The theory of grain boundary (the interface between crystallites, GB) structure has a long history(1) and the concept of GBs undergoing phase transformations was proposed 50 years ago(2,3). The underlying assumption was that multiple stable and metastable states exist for different GB orientations(4-6). The terminology '  complexion'  was recently proposed to distinguish between interfacial states that differ in any equilibrium thermodynamic property(7). Different types of complexion and transitions between complexions have been characterized, mostly in binary or multicomponent systems(8-19). Simulations have provided insight into the phase behaviour of interfaces and shown that GB transitions can occur in many material systems(20-24). However, the direct experimental observation and transformation kinetics of GBs in an elemental metal have remained elusive. Here we demonstrate atomic-scale GB phase coexistence and transformations at symmetric and asymmetric [111 over bar ] tilt GBs in elemental copper. Atomic-resolution imaging reveals the coexistence of two different structures at sigma 19b GBs (where sigma 19 is the density of coincident sites and b is a GB variant), in agreement with evolutionary GB structure search and clustering analysis(21,25,26). We also use finite-temperature molecular dynamics simulations to explore the coexistence and transformation kinetics of these GB phases. Our results demonstrate how GB phases can be kinetically trapped, enabling atomic-scale room-temperature observations. Our work paves the way for atomic-scale in situ studies of metallic GB phase transformations, which were previously detected only indirectly(9,15,27-29), through their influence on abnormal grain growth, non-Arrhenius-type diffusion or liquid metal embrittlement.


  
Spatio-temporal drought patterns of multiple drought indices based on precipitation and soil moisture: A case study in South Korea 期刊论文
INTERNATIONAL JOURNAL OF CLIMATOLOGY, 2019, 39 (12) : 4669-4687
作者:  Kwon, Moonhyuk;  Kwon, Hyun-Han;  Han, Dawei
收藏  |  浏览/下载:15/0  |  提交时间:2019/11/27
clustering analysis  multivariate drought index  quantile regression  SPI  SSI  
Using hybrid weighting-clustering approach for regional frequency analysis of maximum 24-hr rainfall based on climatic, geographical, and statistical attributes 期刊论文
INTERNATIONAL JOURNAL OF CLIMATOLOGY, 2019, 39 (11) : 4413-4428
作者:  Fathian, Farshad;  Dehghan, Zohreh
收藏  |  浏览/下载:16/0  |  提交时间:2019/11/27
attributes  Lake Urmia Basin  maximum 24-hr rainfall  regional frequency analysis  weighting-clustering approach  
A novel global urban typology framework for sustainable mobility futures 期刊论文
ENVIRONMENTAL RESEARCH LETTERS, 2019, 14 (9)
作者:  Oke, Jimi B.;  Aboutaleb, Youssef M.;  Akkinepally, Arun;  Azevedo, Carlos Lima;  Han, Yafei;  Zegras, P. Christopher;  Ferreira, Joseph;  Ben-Akiva, Moshe E.
收藏  |  浏览/下载:20/0  |  提交时间:2019/11/27
urban typologies  sustainable mobility  cities  clustering  data mining  factor analysis  
Informing Future Risks of Record-Level Rainfall in the United States 期刊论文
GEOPHYSICAL RESEARCH LETTERS, 2019, 46 (7) : 3963-3972
作者:  Sanderson, Benjamin M.;  Wobus, Cameron;  Mills, Dave;  Zarakas, Claire;  Crimmins, Allison;  Sarofim, Marcus C.;  Weaver, Chris
收藏  |  浏览/下载:17/0  |  提交时间:2019/11/26
extreme rainfall  climate change  clustering  extreme value analysis  record precipitation  
The Angola Low: relationship with southern African rainfall and ENSO 期刊论文
CLIMATE DYNAMICS, 2019, 52: 1783-1803
作者:  Cretat, Julien;  Pohl, Benjamin;  Dieppois, Bastien;  Berthou, Segolene;  Pergaud, Julien
收藏  |  浏览/下载:18/0  |  提交时间:2019/04/09
Angola Low  Clustering analysis  Daily rainfall  ENSO  Interannual variability  Southern Africa  
Methodology for optimizing a photosynthetically active radiation monitoring network from satellite-derived estimations: A case study over mainland Spain 期刊论文
ATMOSPHERIC RESEARCH, 2018, 212: 227-239
作者:  Vindel, J. M.;  Valenzuela, R. X.;  Navarro, A. A.;  Zarzalejo, L. F.
收藏  |  浏览/下载:13/0  |  提交时间:2019/04/09
Photosynthetically active radiation  Clustering analysis  K-means algorithm  
Environmentally-Targeted Sectors and Linkages in the Global Supply-Chain Complexity of Transport Equipment 期刊论文
ECOLOGICAL ECONOMICS, 2018, 150: 177-183
作者:  Tokito, Shohei
收藏  |  浏览/下载:12/0  |  提交时间:2019/04/09
Global supply chain complexity  CO2 emissions  Input-output clustering analysis  Structural path betweenness analysis  International trade  Climate mitigation policy  
The nationwide characterization and modeling of local energy systems: Quantifying the role of decentralized generation and energy resources in future communities 期刊论文
ENERGY POLICY, 2018, 118: 516-533
作者:  Yazdanie, Mashael;  Densing, Martin;  Wokaun, Alexander
收藏  |  浏览/下载:8/0  |  提交时间:2019/04/09
Clustering  Cost optimization model  Decentralized energy  Local energy systems analysis  Local energy policy  Future cities  
Spatial clustering of maximum 24-h rainfall over Urmia Lake Basin by new weighting approaches 期刊论文
INTERNATIONAL JOURNAL OF CLIMATOLOGY, 2018, 38 (5) : 2298-2313
作者:  Dehghan, Zohreh;  Eslamian, Seyed Saeid;  Modarres, Reza
收藏  |  浏览/下载:13/0  |  提交时间:2019/04/09
principal component analysis  correlation coefficients  attributes weighting  Ward'  s clustering  Urmia Lake Basin  Iran