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Accelerated discovery of CO2 electrocatalysts using active machine learning 期刊论文
NATURE, 2020, 581 (7807) : 178-+
作者:  Lan, Jun;  Ge, Jiwan;  Yu, Jinfang;  Shan, Sisi;  Zhou, Huan;  Fan, Shilong;  Zhang, Qi;  Shi, Xuanling;  Wang, Qisheng;  Zhang, Linqi;  Wang, Xinquan
收藏  |  浏览/下载:126/0  |  提交时间:2020/07/03

The rapid increase in global energy demand and the need to replace carbon dioxide (CO2)-emitting fossil fuels with renewable sources have driven interest in chemical storage of intermittent solar and wind energy(1,2). Particularly attractive is the electrochemical reduction of CO2 to chemical feedstocks, which uses both CO2 and renewable energy(3-8). Copper has been the predominant electrocatalyst for this reaction when aiming for more valuable multi-carbon products(9-16), and process improvements have been particularly notable when targeting ethylene. However, the energy efficiency and productivity (current density) achieved so far still fall below the values required to produce ethylene at cost-competitive prices. Here we describe Cu-Al electrocatalysts, identified using density functional theory calculations in combination with active machine learning, that efficiently reduce CO2 to ethylene with the highest Faradaic efficiency reported so far. This Faradaic efficiency of over 80 per cent (compared to about 66 per cent for pure Cu) is achieved at a current density of 400 milliamperes per square centimetre (at 1.5 volts versus a reversible hydrogen electrode) and a cathodic-side (half-cell) ethylene power conversion efficiency of 55 +/- 2 per cent at 150 milliamperes per square centimetre. We perform computational studies that suggest that the Cu-Al alloys provide multiple sites and surface orientations with near-optimal CO binding for both efficient and selective CO2 reduction(17). Furthermore, in situ X-ray absorption measurements reveal that Cu and Al enable a favourable Cu coordination environment that enhances C-C dimerization. These findings illustrate the value of computation and machine learning in guiding the experimental exploration of multi-metallic systems that go beyond the limitations of conventional single-metal electrocatalysts.


  
Observation of Bose-Einstein condensates in an Earth-orbiting research lab 期刊论文
NATURE, 2020, 582 (7811) : 103-+
作者:  Yamamoto, Keisuke;  Venida, Anthony;  Yano, Julian;  Biancur, Douglas E.;  Kakiuchi, Miwako;  Gupta, Suprit;  Sohn, Albert S. W.;  Mukhopadhyay, Subhadip;  Lin, Elaine Y.;  Parker, Seth J.;  Banh, Robert S.;  Paulo, Joao A.;  Wen, Kwun Wah;  Debnath, Jayanta;  Kim, Grace E.;  Mancias, Joseph D.;  Fearon, Douglas T.;  Perera, Rushika M.;  Kimmelman, Alec C.
收藏  |  浏览/下载:46/0  |  提交时间:2020/07/03

Quantum mechanics governs the microscopic world, where low mass and momentum reveal a natural wave-particle duality. Magnifying quantum behaviour to macroscopic scales is a major strength of the technique of cooling and trapping atomic gases, in which low momentum is engineered through extremely low temperatures. Advances in this field have achieved such precise control over atomic systems that gravity, often negligible when considering individual atoms, has emerged as a substantial obstacle. In particular, although weaker trapping fields would allow access to lower temperatures(1,2), gravity empties atom traps that are too weak. Additionally, inertial sensors based on cold atoms could reach better sensitivities if the free-fall time of the atoms after release from the trap could be made longer(3). Planetary orbit, specifically the condition of perpetual free-fall, offers to lift cold-atom studies beyond such terrestrial limitations. Here we report production of rubidium Bose-Einstein condensates (BECs) in an Earth-orbiting research laboratory, the Cold Atom Lab. We observe subnanokelvin BECs in weak trapping potentials with free-expansion times extending beyond one second, providing an initial demonstration of the advantages offered by a microgravity environment for cold-atom experiments and verifying the successful operation of this facility. With routine BEC production, continuing operations will support long-term investigations of trap topologies unique to microgravity(4,5), atom-laser sources(6), few-body physics(7,8)and pathfinding techniques for atom-wave interferometry(9-12).


  
Monitoring global education inequality 期刊论文
NATURE, 2020, 580 (7805) : 591-592
作者:  Ledford, Heidi
收藏  |  浏览/下载:16/0  |  提交时间:2020/07/03

Tools have been developed to project inequalities in education around the world to 2030. They reveal that overall inequality will decline, but that all world regions will fall short of achieving universal secondary education.


  
Blowdown disturbance effect on the density, richness and species composition of the seed bank in Central Amazonia 期刊论文
FOREST ECOLOGY AND MANAGEMENT, 2019, 453
作者:  Bordon, Natali Gomes;  Nogueira, Anselmo;  Leal Filho, Niwton;  Higuchi, Niro
收藏  |  浏览/下载:29/0  |  提交时间:2020/02/17
Forest disturbance  Melastomataceae  Large gaps  Araceae  Tree fall  
Combining disdrometer, microscopic photography, and cloud radar to study distributions of hydrometeor types, size and fall velocity 期刊论文
ATMOSPHERIC RESEARCH, 2019, 228: 176-185
作者:  Jia, Xingcan;  Liu, Yangang;  Ding, Deping;  Ma, Xincheng;  Chen, Yichen;  Bi, Kai;  Tian, Ping;  Lu, Chunsong;  Quan, Jiannong
收藏  |  浏览/下载:26/0  |  提交时间:2019/11/27
Hydrometeor fall velocity  Hydrometeor size distribution  PARSIVEL disdrometer  Microscope photography  Cloud radar  
Drivers of lodgepole pine recruitment across a gradient of bark beetle outbreak and wildfire in British Columbia 期刊论文
FOREST ECOLOGY AND MANAGEMENT, 2019, 451
作者:  Talucci, Anna C.;  Lertzman, Ken P.;  Krawchuk, Meg A.
收藏  |  浏览/下载:19/0  |  提交时间:2019/11/27
Resilience  Serotiny  Mountain pine beetle  Fire refugia  Seedlings  Fire severity  Snag fall  Postfire climate  
The value of small forest fragments and urban tree canopy for Neotropical migrant birds during winter and migration seasons in Latin American countries: A systematic review 期刊论文
LANDSCAPE AND URBAN PLANNING, 2019, 190
作者:  David Amaya-Espinel, Juan;  Hostetler, Mark E.
收藏  |  浏览/下载:12/0  |  提交时间:2019/11/27
Habitat remnants  Urban areas  Residential areas  Fall/spring migration  Stopover habitat  
Increased Fall Precipitation in the Southeastern United States Driven by Higher-Intensity, Frontal Precipitation 期刊论文
GEOPHYSICAL RESEARCH LETTERS, 2019, 46 (14) : 8300-8309
作者:  Bishop, Daniel A.;  Williams, A. Park;  Seager, Richard
收藏  |  浏览/下载:11/0  |  提交时间:2019/11/27
extreme precipitation  frontal  tropical cyclone  fall  southeastern United States  flood  
Autumn bird migration phenology: A potpourri of wind, precipitation and temperature effects 期刊论文
GLOBAL CHANGE BIOLOGY, 2019
作者:  Haest, Birgen;  Hueppop, Ommo;  van de Pol, Martijn;  Bairlein, Franz
收藏  |  浏览/下载:15/0  |  提交时间:2019/11/27
bird migration  environmental plasticity  fall  Helgoland  radar  rainfall  spatiotemporal analysis  time window analysis  
Modelling leaf dispersal and nutrient return in tree species mixtures 期刊论文
FOREST ECOLOGY AND MANAGEMENT, 2019, 436: 68-78
作者:  Nickmans, Hans;  Jonard, Mathieu;  Verheyen, Kris;  Ponette, Quentin
收藏  |  浏览/下载:14/0  |  提交时间:2019/04/09
Nutrient return  Litter fall  Mixture  Oak  Beech