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DOI | 10.1126/science.aat4191 |
Anomalously low dielectric constant of confined water | |
Fumagalli, L.1,2; Esfandiar, A.3; Fabregas, R.4,5; Hu, S.1,2; Ares, P.1,2; Janardanan, A.1,2; Yang, Q.1,2; Radha, B.1,2; Taniguchi, T.6; Watanabe, K.6; Gomila, G.4,5; Novoselov, K. S.1,2; Geim, A. K.1,2 | |
2018-06-22 | |
发表期刊 | SCIENCE
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ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2018 |
卷号 | 360期号:6395页码:1339-+ |
文章类型 | Article |
语种 | 英语 |
国家 | England; Iran; Spain; Japan |
英文摘要 | The dielectric constant epsilon of interfacial water has been predicted to be smaller than that of bulk water (epsilon approximate to 80) because the rotational freedom of water dipoles is expected to decrease near surfaces, yet experimental evidence is lacking. We report local capacitance measurements for water confined between two atomically flat walls separated by various distances down to 1 nanometer. Our experiments reveal the presence of an interfacial layer with vanishingly small polarization such that its out-of-plane e is only similar to 2. The electrically dead layer is found to be two to three molecules thick. These results provide much-needed feedback for theories describing water-mediated surface interactions and the behavior of interfacial water, and show a way to investigate the dielectric properties of other fluids and solids under extreme confinement. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000436040600041 |
WOS关键词 | HEXAGONAL BORON-NITRIDE ; ELECTROLYTE-SOLUTIONS ; HYDRATION FORCES ; GRAPHENE ; INTERFACE ; TRANSPORT ; MOLECULES ; FRICTION ; SURFACE |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/198940 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | 1.Univ Manchester, Sch Phys & Astron, Manchester M13 9PL, Lancs, England; 2.Univ Manchester, Natl Graphene Inst, Manchester M13 9PL, Lancs, England; 3.Sharif Univ Technol, Dept Phys, POB 11155-9161, Tehran, Iran; 4.Univ Barcelona, Dept Elect, C Marti i Franques 1, E-08028 Barcelona, Spain; 5.Barcelona Inst Sci & Technol, Inst Bioengn Catalunya, C Baldiri i Reixac 15-21, Barcelona 08028, Spain; 6.Natl Inst Mat Sci, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan |
推荐引用方式 GB/T 7714 | Fumagalli, L.,Esfandiar, A.,Fabregas, R.,et al. Anomalously low dielectric constant of confined water[J]. SCIENCE,2018,360(6395):1339-+. |
APA | Fumagalli, L..,Esfandiar, A..,Fabregas, R..,Hu, S..,Ares, P..,...&Geim, A. K..(2018).Anomalously low dielectric constant of confined water.SCIENCE,360(6395),1339-+. |
MLA | Fumagalli, L.,et al."Anomalously low dielectric constant of confined water".SCIENCE 360.6395(2018):1339-+. |
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