GSTDTAP  > 地球科学
DOI10.1126/science.aat4191
Anomalously low dielectric constant of confined water
Fumagalli, L.1,2; Esfandiar, A.3; Fabregas, R.4,5; Hu, S.1,2; Ares, P.1,2; Janardanan, A.1,2; Yang, Q.1,2; Radha, B.1,2; Taniguchi, T.6; Watanabe, K.6; Gomila, G.4,5; Novoselov, K. S.1,2; Geim, A. K.1,2
2018-06-22
发表期刊SCIENCE
ISSN0036-8075
EISSN1095-9203
出版年2018
卷号360期号:6395页码:1339-+
文章类型Article
语种英语
国家England; Iran; Spain; Japan
英文摘要

The dielectric constant epsilon of interfacial water has been predicted to be smaller than that of bulk water (epsilon approximate to 80) because the rotational freedom of water dipoles is expected to decrease near surfaces, yet experimental evidence is lacking. We report local capacitance measurements for water confined between two atomically flat walls separated by various distances down to 1 nanometer. Our experiments reveal the presence of an interfacial layer with vanishingly small polarization such that its out-of-plane e is only similar to 2. The electrically dead layer is found to be two to three molecules thick. These results provide much-needed feedback for theories describing water-mediated surface interactions and the behavior of interfacial water, and show a way to investigate the dielectric properties of other fluids and solids under extreme confinement.


领域地球科学 ; 气候变化 ; 资源环境
收录类别SCI-E
WOS记录号WOS:000436040600041
WOS关键词HEXAGONAL BORON-NITRIDE ; ELECTROLYTE-SOLUTIONS ; HYDRATION FORCES ; GRAPHENE ; INTERFACE ; TRANSPORT ; MOLECULES ; FRICTION ; SURFACE
WOS类目Multidisciplinary Sciences
WOS研究方向Science & Technology - Other Topics
引用统计
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/198940
专题地球科学
资源环境科学
气候变化
作者单位1.Univ Manchester, Sch Phys & Astron, Manchester M13 9PL, Lancs, England;
2.Univ Manchester, Natl Graphene Inst, Manchester M13 9PL, Lancs, England;
3.Sharif Univ Technol, Dept Phys, POB 11155-9161, Tehran, Iran;
4.Univ Barcelona, Dept Elect, C Marti i Franques 1, E-08028 Barcelona, Spain;
5.Barcelona Inst Sci & Technol, Inst Bioengn Catalunya, C Baldiri i Reixac 15-21, Barcelona 08028, Spain;
6.Natl Inst Mat Sci, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
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GB/T 7714
Fumagalli, L.,Esfandiar, A.,Fabregas, R.,et al. Anomalously low dielectric constant of confined water[J]. SCIENCE,2018,360(6395):1339-+.
APA Fumagalli, L..,Esfandiar, A..,Fabregas, R..,Hu, S..,Ares, P..,...&Geim, A. K..(2018).Anomalously low dielectric constant of confined water.SCIENCE,360(6395),1339-+.
MLA Fumagalli, L.,et al."Anomalously low dielectric constant of confined water".SCIENCE 360.6395(2018):1339-+.
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