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DOI | 10.1126/science.aay9972 |
Rational design of layered oxide materials for sodium-ion batteries | |
Chenglong Zhao; Qidi Wang; Zhenpeng Yao; Jianlin Wang; Benjamín Sánchez-Lengeling; Feixiang Ding; Xingguo Qi; Yaxiang Lu; Xuedong Bai; Baohua Li; Hong Li; Alán Aspuru-Guzik; Xuejie Huang; Claude Delmas; Marnix Wagemaker; Liquan Chen; Yong-Sheng Hu | |
2020-11-06 | |
发表期刊 | Science |
出版年 | 2020 |
英文摘要 | Layered metal oxides such as lithium cobalt oxide have attracted great attention for rechargeable batteries. In lithium cells, only the octahedral structure forms, but in sodium cells, trigonal prismatic structures are also possible. However, there is a lack of understanding about how to predict and control the formation of each structure. Zhao et al. used the simple properties of ions, namely their charge and their radius appropriately weighted by stoichiometry, to determine whether sodium in the interlayers between the transition metal or other ion-oxide layers remain octahedral rather than switching over to trigonal prismatic coordination. Science , this issue p. [708][1] Sodium-ion batteries have captured widespread attention for grid-scale energy storage owing to the natural abundance of sodium. The performance of such batteries is limited by available electrode materials, especially for sodium-ion layered oxides, motivating the exploration of high compositional diversity. How the composition determines the structural chemistry is decisive for the electrochemical performance but very challenging to predict, especially for complex compositions. We introduce the “cationic potential” that captures the key interactions of layered materials and makes it possible to predict the stacking structures. This is demonstrated through the rational design and preparation of layered electrode materials with improved performance. As the stacking structure determines the functional properties, this methodology offers a solution toward the design of alkali metal layered oxides. [1]: /lookup/doi/10.1126/science.aay9972 |
领域 | 气候变化 ; 资源环境 |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/302001 |
专题 | 气候变化 资源环境科学 |
推荐引用方式 GB/T 7714 | Chenglong Zhao,Qidi Wang,Zhenpeng Yao,et al. Rational design of layered oxide materials for sodium-ion batteries[J]. Science,2020. |
APA | Chenglong Zhao.,Qidi Wang.,Zhenpeng Yao.,Jianlin Wang.,Benjamín Sánchez-Lengeling.,...&Yong-Sheng Hu.(2020).Rational design of layered oxide materials for sodium-ion batteries.Science. |
MLA | Chenglong Zhao,et al."Rational design of layered oxide materials for sodium-ion batteries".Science (2020). |
条目包含的文件 | 条目无相关文件。 |
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