Laboratory Constraints on the Stability of Petroleum at Elevated Temperatures: Implications for the Origin of Natural Gas

doi:10.2172/1008348

GSTDTAP > 地球科学

DOI	10.2172/1008348
报告编号	DOE ER14746 - Final Report
来源ID	OSTI ID: 1008348
	Laboratory Constraints on the Stability of Petroleum at Elevated Temperatures: Implications for the Origin of Natural Gas
	Lindberg, Michael J.
	2011-03-14
出版年	2011
语种	英语
国家	美国
领域	地球科学
英文摘要	Results of prior DOE supported research conducted at the Woods Hole Oceanographic Institution have demonstrated the participation of sedimentary minerals and water as reactants and catalysts in chemical transformations associated with the degradation of oil and the formation of low molecular weight organic compounds. The occurrence of such processes in natural environments can be difficult to recognize because the composition of organic alteration products may not be substantially different than those produced by thermal cracking. The goals of this study were the development of diagnostic tools based on hydrogen and carbon isotopes that can be used to identify geochemical processes responsible for the formation of thermogenic natural gas. In addition, our activities were expanded to include experimental investigation of CO2 reduction in aqueous systems at elevated temperature and pressures and an assessment of microbial activity in relatively low temperature (<70Â°C) natural gas reservoirs in southeastern Oklahoma. Specific objectives included: A laboratory investigation of geochemical processes that regulate the hydrogen isotope composition of low molecular weight hydrocarbons in natural gas at elevated temperatures and pressures. A laboratory investigation of factors that regulate the carbon isotope composition of organic acids in basinal brines. A laboratory assessment of the role of methanol during reduction of CO2 to CH4 under hydrothermal conditions. Characterization of microbial ecosystems in coproduced fluids from the Potato Hills gas field to assess the role of microbes in the generation of natural gas.
英文关键词	Natural gas formation petroleum stability hydrogen isotopes carbon isotopes subsurface biosphere isotope exchange microbiology methane generation abiotic synthesis methanol stability.
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来源平台	US Department of Energy (DOE)
引用统计
文献类型	科技报告
条目标识符	http://119.78.100.173/C666/handle/2XK7JSWQ/5359
专题	地球科学
推荐引用方式 GB/T 7714	Lindberg, Michael J.. Laboratory Constraints on the Stability of Petroleum at Elevated Temperatures: Implications for the Origin of Natural Gas,2011.